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- W2783459189 endingPage "431" @default.
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- W2783459189 abstract "4-Trifluoromethyl-3-oxo-β-lactams were unexpectedly transformed into 2-[(2,2-difluorovinyl)amino]-2-oxoacetates as major products, accompanied by minor amounts of 2-oxo-2-[(2,2,2-trifluoroethyl)amino]acetates, upon treatment with alkyl halides and triethylamine in DMSO. This peculiar C3-C4 bond fission reactivity was investigated in-depth, from both an experimental and a computational point of view, in order to shed light on the underlying reaction mechanism." @default.
- W2783459189 created "2018-01-26" @default.
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- W2783459189 date "2018-01-29" @default.
- W2783459189 modified "2023-09-23" @default.
- W2783459189 title "Formation of Fluorinated Amido Esters through Unexpected C3−C4 Bond Fission in 4-Trifluoromethyl-3-oxo-β-lactams" @default.
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- W2783459189 doi "https://doi.org/10.1002/asia.201701636" @default.
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