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• W2783509365 abstract "The gas-phase stabilities of Tl + -crown ether complexes and Rb + -crown ether complexes were studied using the electrospray ionization-collision-induced dissociation-tandem mass spectrometry. Tl + and Rb + have identical ionic radii, thus a comparison of the properties of the crown ether complexes with these two cations seems to be justified. The selected crown ethers were 12C4 (it has a cavity smaller than the cation radius), 18C6 (it has a cavity of size similar to the cation radius), 24C8 (it has a cavity greater than the cation radius) and their conjugates. It has been found that the crown ether complexes of stoichiometry 1:1 with Tl + are more or equally stable in the gas phase than the crown ether complexes with Rb + . However, 2:1 complexes with Tl + are less stable than the complexes with Rb + ." @default.
• W2783509365 created "2018-01-26" @default.
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• W2783509365 date "2018-01-10" @default.
• W2783509365 modified "2023-09-24" @default.
• W2783509365 title "Gas-phase relative stabilities of Tl+-crown ether complexes and Rb+-crown ether complexes" @default.
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• W2783509365 doi "https://doi.org/10.1177/1469066717752794" @default.
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