FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2783536969> ?p ?o ?g. }

• W2783536969 endingPage "12868" @default.
• W2783536969 startingPage "12856" @default.
• W2783536969 abstract "The Al/P-based frustrated Lewis pair (FLP) Mes2 P-C(AltBu)2 =C(H)Ph (1; Mes=mesityl) reacted as an efficient two-electron reductant with benzil to afford a cis-enediolate that was coordinated to the FLP through P-O and Al-O bonds and the formation of a seven-membered heterocycle (2). The phosphorus atom is oxidised from +III to +V. Similar heterocycles (3 a to 3 f) were formed if 1 was treated with various enones (acrolein, acrylate, acrylamide). The resulting enolates are bound to the FLP through P-C and Al-O bonds. Cyclopropenone gave an adduct (4) with the C=O bond coordinated by P and Al. Ynones gave a fascinating variety of different structures. 1,3-Diphenylprop-2-yn-1-one afforded a remarkable allene-type moiety with two cumulated C=C bonds (5); 3-hexyn-2-one yielded a ligand with two conjugated C=C bonds by C-H bond activation at the carbonyl methyl group (7); and 4-(trimethylsilyl)-3-butyn-2-one reacted by C-H bond cleavage, formation of an enolate group with a terminal C=C bond, and shift of the proton to the P atom (8). The C≡C bond was not affected. Allene compound 5 rearranged at elevated temperature and in daylight through the formation of a tricyclic compound by C-H bond activation and C-C bond formation. DFT calculations on this unusual rearrangement suggest insertion of the central allene C atom into the C-H bond of a methyl group and the intermediate formation of a C3 ring." @default.
• W2783536969 created "2018-01-26" @default.
• W2783536969 creator A5004759032 @default.
• W2783536969 creator A5013168632 @default.
• W2783536969 creator A5019318131 @default.
• W2783536969 creator A5032754495 @default.
• W2783536969 creator A5084898256 @default.
• W2783536969 creator A5088823361 @default.
• W2783536969 date "2018-03-05" @default.
• W2783536969 modified "2023-09-29" @default.
• W2783536969 title "Reactions of an Aluminium/Phosphorus Frustrated Lewis Pair (FLP) with α,β-Unsaturated Carbonyl Compounds: FLPs as Efficient Two-Electron Reductants with the Formation of Enolates, a <i>cis</i> -Enediolate, and an Allene" @default.
• W2783536969 cites W1588703153 @default.
• W2783536969 cites W1678846486 @default.
• W2783536969 cites W1807016999 @default.
• W2783536969 cites W1897198241 @default.
• W2783536969 cites W1965533891 @default.
• W2783536969 cites W1966625637 @default.
• W2783536969 cites W1969321380 @default.
• W2783536969 cites W1984005214 @default.
• W2783536969 cites W1990911611 @default.
• W2783536969 cites W1994567008 @default.
• W2783536969 cites W2001670536 @default.
• W2783536969 cites W2003613806 @default.
• W2783536969 cites W2015241505 @default.
• W2783536969 cites W2021389084 @default.
• W2783536969 cites W2024175762 @default.
• W2783536969 cites W2029779454 @default.
• W2783536969 cites W2032719166 @default.
• W2783536969 cites W2038613461 @default.
• W2783536969 cites W2045173752 @default.
• W2783536969 cites W2053157033 @default.
• W2783536969 cites W2053184623 @default.
• W2783536969 cites W2057753783 @default.
• W2783536969 cites W2060287422 @default.
• W2783536969 cites W2062734576 @default.
• W2783536969 cites W2072009217 @default.
• W2783536969 cites W2073272057 @default.
• W2783536969 cites W2077718990 @default.
• W2783536969 cites W2082690721 @default.
• W2783536969 cites W2084771354 @default.
• W2783536969 cites W2096747776 @default.
• W2783536969 cites W2100605529 @default.
• W2783536969 cites W2112058508 @default.
• W2783536969 cites W2121455509 @default.
• W2783536969 cites W2126552299 @default.
• W2783536969 cites W2126875005 @default.
• W2783536969 cites W2128643931 @default.
• W2783536969 cites W2131350133 @default.
• W2783536969 cites W2132173090 @default.
• W2783536969 cites W2136849497 @default.
• W2783536969 cites W2141754854 @default.
• W2783536969 cites W2143453620 @default.
• W2783536969 cites W2144279151 @default.
• W2783536969 cites W2147304506 @default.
• W2783536969 cites W2150798656 @default.
• W2783536969 cites W2151244894 @default.
• W2783536969 cites W2157063862 @default.
• W2783536969 cites W2166906572 @default.
• W2783536969 cites W2167082108 @default.
• W2783536969 cites W2208724740 @default.
• W2783536969 cites W2234744023 @default.
• W2783536969 cites W2257492138 @default.
• W2783536969 cites W2289533976 @default.
• W2783536969 cites W2296644930 @default.
• W2783536969 cites W2298623631 @default.
• W2783536969 cites W2312455579 @default.
• W2783536969 cites W2319787880 @default.
• W2783536969 cites W2319863753 @default.
• W2783536969 cites W2320290797 @default.
• W2783536969 cites W2322761555 @default.
• W2783536969 cites W2323621950 @default.
• W2783536969 cites W2324565240 @default.
• W2783536969 cites W2325797793 @default.
• W2783536969 cites W2327303995 @default.
• W2783536969 cites W2335081101 @default.
• W2783536969 cites W2343280285 @default.
• W2783536969 cites W2415607014 @default.
• W2783536969 cites W2417336535 @default.
• W2783536969 cites W2463295065 @default.
• W2783536969 cites W2513848205 @default.
• W2783536969 cites W2519555257 @default.
• W2783536969 cites W2556071164 @default.
• W2783536969 cites W2584473618 @default.
• W2783536969 cites W2585274539 @default.
• W2783536969 cites W2594029827 @default.
• W2783536969 cites W2701046605 @default.
• W2783536969 cites W2738704045 @default.
• W2783536969 cites W2744834133 @default.
• W2783536969 cites W2760708312 @default.
• W2783536969 cites W2761988310 @default.
• W2783536969 cites W2769896349 @default.
• W2783536969 cites W4237362857 @default.
• W2783536969 cites W4237868644 @default.
• W2783536969 cites W4244297390 @default.
• W2783536969 cites W4244452341 @default.
• W2783536969 cites W4245964259 @default.
• W2783536969 cites W4255824655 @default.
• W2783536969 doi "https://doi.org/10.1002/chem.201706089" @default.

• next