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- W2783609128 abstract "合成了一个新的配合物[Eu（4-MOBA）3（terpy）（H2O）]2（4-MOBA：4-甲氧基苯甲酸根,terpy：2,2′：6′,2′′-三联吡啶）。采用傅里叶变换红外（FTIR）光谱、元素分析和X射线粉末衍射（XRD）技术对标题配合物进行了表征,用X射线单晶衍射仪测定了配合物的晶体结构,在配合物中每个Eu3＋离子与一个三联吡啶分子、一个水分子和三个羧酸分子结合,配位数为9,羧酸基团的配位模式包含三种：双齿螯合,桥连双齿,单齿。根据热重-差示扫描量热/傅里叶变换红外（TG-DSC/FTIR）联用技术,研究了配合物的热分解机理。配合物的发射光谱显示出Eu3＋离子的特征荧光发射,表明三联吡啶和4-甲氧基苯甲酸在该体系中可作为敏化集团。另外,文中还讨论了配合物对白色念珠菌和大肠杆菌的抑菌活性。" @default.
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- W2783609128 date "2016-01-01" @default.
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- W2783609128 title "Synthesis, Characterization, Thermal Decomposition Mechanism and Properties of the [Eu(4-MOBA)<sub>3</sub>(terpy)(H<sub>2</sub>O)]<sub>2</sub> Complex" @default.
- W2783609128 doi "https://doi.org/10.3866/pku.whxb201602173" @default.
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