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• W2783669057 abstract "2-Aminophenyl-1H-pyrazole has been identified as a viable directing group to promote copper(II)-mediated ortho-selective sp2 C-H bond tandem alkynylation/annulation of anilides with terminal alkynes to offer arylmethylene isoindolinones. Meanwhile, copper(II)-mediated ortho-selective sp2 C-H hydroxylation of anilides has also been optimized as the major reaction pathway by using Cu(OAc)2 as the promoter and 1,1,3,3-tetramethylguanidine as an organic base. Recovery of the directing group was achieved by hydrazinolysis for arylmethylene isoindolinones and basic hydrolysis for the hydroxylation products." @default.
• W2783669057 created "2018-01-26" @default.
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• W2783669057 date "2018-02-01" @default.
• W2783669057 modified "2023-10-03" @default.
• W2783669057 title "Copper(II)-Mediated <i>ortho</i>-Selective C(sp²)–H Tandem Alkynylation/Annulation and <i>ortho</i>-Hydroxylation of Anilides with 2-Aminophenyl-1<i>H</i>-pyrazole as a Directing Group" @default.
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• W2783669057 doi "https://doi.org/10.1021/acs.joc.7b02893" @default.
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