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- W2783703525 abstract "We synthesized star-shaped 18-arm polystyrene-block-poly(3-dodecylthiophene) copolymers ((PS-b-P3DDT)18) having lamellar microdomains, based on the cyclodextrin (CD) core. Without any surface modifications on a silicon substrate, thin films of (PS-b-P3DDT)18 showed vertically oriented lamellar microdomains by thermal annealing. This is attributed to the entropic penalty induced by star-shaped chain architecture. In contrast, a parallel orientation was observed in the film morphology of the corresponding linear PS-b-P3DDT. We also found that the P3DDT crystals were confined in the lamellar microdomains of (PS-b-P3DDT)18 as edge-on structure." @default.
- W2783703525 created "2018-01-26" @default.
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- W2783703525 date "2018-06-20" @default.
- W2783703525 modified "2023-10-18" @default.
- W2783703525 title "Vertically Oriented Nanostructures of Poly(3-dodecylthiophene)-Containing Rod–Coil Block Copolymers" @default.
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- W2783703525 doi "https://doi.org/10.1021/acs.macromol.7b02739" @default.
- W2783703525 hasPublicationYear "2018" @default.
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