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- W2783757337 endingPage "815" @default.
- W2783757337 startingPage "801" @default.
- W2783757337 abstract "Zwitterion ionic liquids (ZIs) are compounds in which both counterions are covalently tethered, conferring them with unique characteristics; however, most of their properties are still unknown, representing a bottleneck to exploit their practical applications. Herein, the molecular and fluid properties of ZIs and their mixtures were explored by means of quantum chemical analysis based on the density functional theory (DFT) and COSMO-RS method, and compared against homologous ionic liquids (ILs) to provide a comprehensive overview of the effect of the distinct structures on their physicochemical and thermodynamic behavior. Overall, ZIs were revealed as compounds with higher polarity and stronger hydrogen-bonding capacity, implying higher density, viscosity, melting point, and even lower volatility than structurally similar ILs. The phase equilibrium of binary and ternary systems supports stronger attractive interactions between ZIs and polar compounds, whereas higher liquid-liquid immiscibility with nonpolar compounds may be expected. Ultimately, the performance of ZIs in the wider context of separation processes is illustrated, while providing molecular insights to allow their selection and design for relevant applications." @default.
- W2783757337 created "2018-01-26" @default.
- W2783757337 creator A5014031238 @default.
- W2783757337 creator A5023007533 @default.
- W2783757337 creator A5054545335 @default.
- W2783757337 creator A5066282150 @default.
- W2783757337 date "2018-02-28" @default.
- W2783757337 modified "2023-10-18" @default.
- W2783757337 title "Molecular and Thermodynamic Properties of Zwitterions versus Ionic Liquids: A Comprehensive Computational Analysis to Develop Advanced Separation Processes" @default.
- W2783757337 cites W1886228341 @default.
- W2783757337 cites W1964304665 @default.
- W2783757337 cites W1965200916 @default.
- W2783757337 cites W1970452813 @default.
- W2783757337 cites W1981392543 @default.
- W2783757337 cites W1985087154 @default.
- W2783757337 cites W1988822611 @default.
- W2783757337 cites W1991283550 @default.
- W2783757337 cites W1995615380 @default.
- W2783757337 cites W1997151511 @default.
- W2783757337 cites W2003770424 @default.
- W2783757337 cites W2009163984 @default.
- W2783757337 cites W2015435291 @default.
- W2783757337 cites W2016800344 @default.
- W2783757337 cites W2020768815 @default.
- W2783757337 cites W2020959202 @default.
- W2783757337 cites W202162594 @default.
- W2783757337 cites W2022315367 @default.
- W2783757337 cites W2037082757 @default.
- W2783757337 cites W2038935808 @default.
- W2783757337 cites W2041753910 @default.
- W2783757337 cites W2042460654 @default.
- W2783757337 cites W2049696251 @default.
- W2783757337 cites W2051465614 @default.
- W2783757337 cites W2053394268 @default.
- W2783757337 cites W2061011942 @default.
- W2783757337 cites W2061643009 @default.
- W2783757337 cites W2062932961 @default.
- W2783757337 cites W2063955872 @default.
- W2783757337 cites W2065201227 @default.
- W2783757337 cites W2065278298 @default.
- W2783757337 cites W2066624443 @default.
- W2783757337 cites W2067534423 @default.
- W2783757337 cites W2069002738 @default.
- W2783757337 cites W2071174105 @default.
- W2783757337 cites W2073328513 @default.
- W2783757337 cites W2074455772 @default.
- W2783757337 cites W2076715917 @default.
- W2783757337 cites W2077430440 @default.
- W2783757337 cites W2085341294 @default.
- W2783757337 cites W2086957099 @default.
- W2783757337 cites W2090135568 @default.
- W2783757337 cites W2093414302 @default.
- W2783757337 cites W2093486004 @default.
- W2783757337 cites W2098998854 @default.
- W2783757337 cites W2105065508 @default.
- W2783757337 cites W2105881736 @default.
- W2783757337 cites W2107199569 @default.
- W2783757337 cites W2122250145 @default.
- W2783757337 cites W2122813875 @default.
- W2783757337 cites W2133521109 @default.
- W2783757337 cites W2134846164 @default.
- W2783757337 cites W2142078652 @default.
- W2783757337 cites W2145021857 @default.
- W2783757337 cites W2161515822 @default.
- W2783757337 cites W2162235098 @default.
- W2783757337 cites W2163174291 @default.
- W2783757337 cites W2165703451 @default.
- W2783757337 cites W2166219224 @default.
- W2783757337 cites W2197224450 @default.
- W2783757337 cites W2237683282 @default.
- W2783757337 cites W2273320747 @default.
- W2783757337 cites W2282931321 @default.
- W2783757337 cites W2294355217 @default.
- W2783757337 cites W2295872449 @default.
- W2783757337 cites W2302396902 @default.
- W2783757337 cites W2312764592 @default.
- W2783757337 cites W2314014622 @default.
- W2783757337 cites W2322715610 @default.
- W2783757337 cites W2323827716 @default.
- W2783757337 cites W2326685804 @default.
- W2783757337 cites W2327561936 @default.
- W2783757337 cites W2334149009 @default.
- W2783757337 cites W2338976343 @default.
- W2783757337 cites W2355834273 @default.
- W2783757337 cites W2411076832 @default.
- W2783757337 cites W2473888065 @default.
- W2783757337 cites W2474889083 @default.
- W2783757337 cites W2490893484 @default.
- W2783757337 cites W2511747885 @default.
- W2783757337 cites W2515487652 @default.
- W2783757337 cites W2533257396 @default.
- W2783757337 cites W2555914817 @default.
- W2783757337 cites W2558559315 @default.
- W2783757337 cites W2561481995 @default.
- W2783757337 cites W2565666232 @default.
- W2783757337 cites W2572889681 @default.
- W2783757337 cites W2575597094 @default.
- W2783757337 cites W2582734059 @default.