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- W2783759794 abstract "A fast and efficient methodology for the selective oxidation of sugars into corresponding sodium aldonates is herein reported. Hydrogen peroxide was used as a cheap oxidant and electron scavenger, in the presence of only 0.003–0.006 mol % of gold in basic conditions. Three photocatalysts were studied, namely Au/Al2O3, Au/TiO2, and Au/CeO2, the latter being the most efficient (TOF > 750 000 h–1) and perfectly selective. Only a 10 min exposition under standard incident sunlight irradiation (A.M.1.5G conditions, 100 mW/cm2) affords total conversion of glucose into the corresponding sodium gluconate. Demonstrating its versatility, this methodology was successfully applied to a variety of oligosaccharides leading to the corresponding aldonates in quantitative yield and high purity (>95%) without any purification step. The photocatalyst was recovered by simple filtration and reused 5 times leading to the same conversion and selectivity after 10 min of illumination." @default.
- W2783759794 created "2018-01-26" @default.
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- W2783759794 date "2018-01-25" @default.
- W2783759794 modified "2023-10-09" @default.
- W2783759794 title "Gold Catalysis and Photoactivation: A Fast and Selective Procedure for the Oxidation of Free Sugars" @default.
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- W2783759794 doi "https://doi.org/10.1021/acscatal.7b03394" @default.
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