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- W2783953605 abstract "An efficient synthesis of quinazolines based on an iron-catalyzed C(sp3)-H oxidation and intramolecular C–N bond formation using tert-BuOOH as the terminal oxidant is described. The reaction of readily available 2-alkylamino benzonitriles with various organometallic reagents led to 2-alkylamino N–H ketimine species. The FeCl2-catalyzed C(sp3)-H oxidation of the alkyl group employing tert-BuOOH followed by intramolecular C–N bond formation and aromatization afforded a wide variety of 2,4-disubstituted quinazolines in good to excellent yields." @default.
- W2783953605 created "2018-01-26" @default.
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- W2783953605 date "2018-01-29" @default.
- W2783953605 modified "2023-09-23" @default.
- W2783953605 title "Synthesis of Quinazolines via an Iron-Catalyzed Oxidative Amination of N–H Ketimines" @default.
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- W2783953605 doi "https://doi.org/10.1021/acs.joc.7b02943" @default.
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