Matches in SemOpenAlex for { <https://semopenalex.org/work/W2783965897> ?p ?o ?g. }
Showing items 1 to 71 of
71
with 100 items per page.
- W2783965897 abstract "The solvation parameter model is used to characterize the retention properties of a poly(methylphenylsiloxane) column Rxi-50 over the temperature range 60–240 ◦ C. The smooth variation of the system constants with temperature affords a general picture of how the relative importance of the different intermolecular interactions change with temperature. The system constants and retention factors for varied compounds are compared with those for Rtx-50 prepared with a similar stationary phase but using a different surface deactivation technique. The two columns are shown to be nearly selectivity equivalent. The Rtx-50 column is slightly more cohesive, dipolar/polarizable and hydrogen-bond basic than Rxi-50, while Rxi-50 is slightly more electron lone pair attractive and hydrogen-bond acidic. Only the difference in hydrogen-bond acidity can be identified with some certainty as related to the difference in deactivation processes. For compounds with a separation greater than 0.2 retention factor units on Rtx-50, it should be relatively straightforward to achieve an acceptable separation for the same compounds on Rxi-50. © 2008 Elsevier B.V. All rights reserved." @default.
- W2783965897 created "2018-01-26" @default.
- W2783965897 creator A5040129806 @default.
- W2783965897 creator A5042984744 @default.
- W2783965897 date "2008-01-01" @default.
- W2783965897 modified "2023-09-23" @default.
- W2783965897 title "Short communication Selectivity equivalence of two poly(methylphenylsiloxane) open-tubular columns prepared with different deactivation techniques for gas chromatography" @default.
- W2783965897 cites W1495312837 @default.
- W2783965897 cites W2003846233 @default.
- W2783965897 hasPublicationYear "2008" @default.
- W2783965897 type Work @default.
- W2783965897 sameAs 2783965897 @default.
- W2783965897 citedByCount "0" @default.
- W2783965897 crossrefType "journal-article" @default.
- W2783965897 hasAuthorship W2783965897A5040129806 @default.
- W2783965897 hasAuthorship W2783965897A5042984744 @default.
- W2783965897 hasConcept C112887158 @default.
- W2783965897 hasConcept C113196181 @default.
- W2783965897 hasConcept C118792377 @default.
- W2783965897 hasConcept C123460561 @default.
- W2783965897 hasConcept C139287275 @default.
- W2783965897 hasConcept C148093993 @default.
- W2783965897 hasConcept C161790260 @default.
- W2783965897 hasConcept C166950319 @default.
- W2783965897 hasConcept C178790620 @default.
- W2783965897 hasConcept C185592680 @default.
- W2783965897 hasConcept C32909587 @default.
- W2783965897 hasConcept C43617362 @default.
- W2783965897 hasConcept C46000676 @default.
- W2783965897 hasConcept C512968161 @default.
- W2783965897 hasConceptScore W2783965897C112887158 @default.
- W2783965897 hasConceptScore W2783965897C113196181 @default.
- W2783965897 hasConceptScore W2783965897C118792377 @default.
- W2783965897 hasConceptScore W2783965897C123460561 @default.
- W2783965897 hasConceptScore W2783965897C139287275 @default.
- W2783965897 hasConceptScore W2783965897C148093993 @default.
- W2783965897 hasConceptScore W2783965897C161790260 @default.
- W2783965897 hasConceptScore W2783965897C166950319 @default.
- W2783965897 hasConceptScore W2783965897C178790620 @default.
- W2783965897 hasConceptScore W2783965897C185592680 @default.
- W2783965897 hasConceptScore W2783965897C32909587 @default.
- W2783965897 hasConceptScore W2783965897C43617362 @default.
- W2783965897 hasConceptScore W2783965897C46000676 @default.
- W2783965897 hasConceptScore W2783965897C512968161 @default.
- W2783965897 hasLocation W27839658971 @default.
- W2783965897 hasOpenAccess W2783965897 @default.
- W2783965897 hasPrimaryLocation W27839658971 @default.
- W2783965897 hasRelatedWork W125173631 @default.
- W2783965897 hasRelatedWork W1553102523 @default.
- W2783965897 hasRelatedWork W1970618160 @default.
- W2783965897 hasRelatedWork W1973491893 @default.
- W2783965897 hasRelatedWork W1973711498 @default.
- W2783965897 hasRelatedWork W1978175866 @default.
- W2783965897 hasRelatedWork W1987938457 @default.
- W2783965897 hasRelatedWork W2002841795 @default.
- W2783965897 hasRelatedWork W2042546355 @default.
- W2783965897 hasRelatedWork W2051081607 @default.
- W2783965897 hasRelatedWork W2056848359 @default.
- W2783965897 hasRelatedWork W2057988871 @default.
- W2783965897 hasRelatedWork W2059960693 @default.
- W2783965897 hasRelatedWork W2076781382 @default.
- W2783965897 hasRelatedWork W2078777124 @default.
- W2783965897 hasRelatedWork W2081156179 @default.
- W2783965897 hasRelatedWork W2093802875 @default.
- W2783965897 hasRelatedWork W2267292959 @default.
- W2783965897 hasRelatedWork W2737665291 @default.
- W2783965897 hasRelatedWork W2994672469 @default.
- W2783965897 isParatext "false" @default.
- W2783965897 isRetracted "false" @default.
- W2783965897 magId "2783965897" @default.
- W2783965897 workType "article" @default.