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- W2783992498 abstract "Quantitative X-ray photoelectron spectroscopic (XPS) analysis combined with spectral modeling of photoelectrons can be valuable while investigating the surface chemistry of nanoparticles (NPs) with different morphologies. Herein, with the use of NIST Simulation of Electron Spectra for Surface Analysis (SESSA), a comparative analysis of experimental and simulated photoelectron peak intensities in gold nanoparticles (AuNPs) of different morphologies is presented. Three sets of supported AuNPs with different morphologies were selected from a series of as synthesized Au-TiO2 catalyst samples. Using transmission electron microscopy (TEM) analyzed morphological information on the AuNPs as input model parameters in SESSA, XPS spectra were generated from the respective input NP morphologies. A degree of greater mismatch between SESSA simulated and experimental XPS spectra was observed while using the TEM obtained average diameter of the nanoparticles. The degree of mismatch lowered when the true nonspherical shap..." @default.
- W2783992498 created "2018-01-26" @default.
- W2783992498 creator A5046515209 @default.
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- W2783992498 date "2018-03-13" @default.
- W2783992498 modified "2023-10-12" @default.
- W2783992498 title "Correction to Impact of Nonideal Nanoparticles on X-ray Photoelectron Spectroscopic Quantitation: An Investigation Using Simulation and Modeling of Gold Nanoparticles" @default.
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- W2783992498 doi "https://doi.org/10.1021/acs.analchem.8b00832" @default.
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