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• W2784111191 abstract "In this paper, we show that carboxylic acid-functionalized molecules can be patterned by photochemical microcontact printing on tetrazole-terminated self-assembled monolayers. Upon irradiation, tetrazoles eliminate nitrogen to form highly reactive nitrile imines, which can be ligated with several different nucleophiles, carboxylic acids being the most reactive. As a proof of concept, we immobilized trifluoroacetic acid to monitor the reaction with X-ray photoelectron spectroscopy. Moreover, we also immobilized peptides and fabricated carbohydrate-lectin as well as biotin-streptavidin microarrays using this method. Surface-patterning was demonstrated by fluorescence microscopy and time-of-flight secondary ion mass spectrometry." @default.
• W2784111191 created "2018-01-26" @default.
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• W2784111191 date "2018-01-26" @default.
• W2784111191 modified "2023-10-04" @default.
• W2784111191 title "Surface Functionalization with Carboxylic Acids by Photochemical Microcontact Printing and Tetrazole Chemistry" @default.
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• W2784111191 doi "https://doi.org/10.1021/acs.langmuir.7b03678" @default.
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