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- W2784328088 abstract "Donor-acceptor cyclopropanes were reacted under Lewis acid catalysis with 3-thioxocyclobutanones as surrogates for disubstituted thioketenes. A broad scope of 2-substituted tetrahydrothiophenes with a semicyclic double bond was obtained under mild conditions with high functional group tolerance and in excellent yield. A sequence of a formal [3 + 2]-cycloaddition followed by the subsequent release of disubstituted ketene is postulated as the mechanism." @default.
- W2784328088 created "2018-01-26" @default.
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- W2784328088 date "2018-01-18" @default.
- W2784328088 modified "2023-10-18" @default.
- W2784328088 title "Formal Insertion of Thioketenes into Donor–Acceptor Cyclopropanes by Lewis Acid Catalysis" @default.
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- W2784328088 doi "https://doi.org/10.1021/acs.orglett.7b03961" @default.
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