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- W2784839170 abstract "We report on the synthesis of single crystalline and polycrystalline samples of Ce$_{3-x}$Mg$_x$Co$_9$ solid solution ($0leq x lesssim 1.4$) and characterization of their structural and magnetic properties. The crystal structure remains rhombohedral in the whole composition range and Mg partially replaces Ce in the 6textit{c} site of the CeCo$_3$ structure. Ferromagnetism is induced by Mg substitutions starting as low as $x=0.18$ and reaching a Curie temperature as high as $450$,K for $x=1.35$. Measurements on single crystals with $x=1.34$ and $T_textrm{C}=440$,K indicate an axial magnetic anisotropy with the anisotropy field of $6$,T and a magnetization of $6$,$mu_B/$f.u. at $300$,K. Coercicity is observed in the polycrystalline samples consistent with the observed axial magnetic anisotropy. Our discovery of ferromagnetism with large axial magnetic anisotropy induced by substituting a rare-earth element by Mg is a very promising result in the search of inexpensive permanent-magnet materials and suggests other non-magnetic phases, similar to CeCo$_3$, may also conceal nearby ferromagnetic phases." @default.
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- W2784839170 date "2018-01-21" @default.
- W2784839170 modified "2023-10-16" @default.
- W2784839170 title "Ce$_{3-x}$Mg$_x$Co$_{9}$: transformation of a Pauli paramagnet into a strong permanent magnet" @default.
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