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• W2785015766 abstract "Two new copper-rich antimonide polar intermetallics, Sr4Cu25.37(18)Sb12 and Eu4Cu26.06(13)Sb12, were synthesized through high-temperature flux reactions, and their structures were accurately determined through the single-crystal X-ray diffraction technique. Sr4Cu25.37(18)Sb12 and Eu4Cu26.06(13)Sb12 crystallize in their own structure type with an orthorhombic space group Cmcm (No. 63) (cell parameters: a = 4.3200(7)/4.2874(7) A, b = 14.528(2)/14.611(2) A, c = 12.2594(19)/12.1946(19) A, respectively). The anionic frameworks of these compounds can be described as composed of 16-vertex Cu10Sb6 polyhedra, which form edge-sharing cages filled with the cations. A simple electron counting implies that the on-stoichiometric composition as Sr4Cu28Sb12 or Eu4Cu28Sb12 should be electron-precise; however, metallic conducting properties were suggested by the measured electrical transport properties as well as by the extensive Cu vacancies in the structure. Magnetic susceptibility measurements on Eu4Cu26.06(13)Sb12 indi..." @default.
• W2785015766 created "2018-02-02" @default.
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• W2785015766 date "2018-01-27" @default.
• W2785015766 modified "2023-09-25" @default.
• W2785015766 title "Sr₄Cu_25.37(18)Sb₁₂ and Eu₄Cu_26.06(13)Sb₁₂: Copper-Rich Antimonide Intermetallics with Cage Structure" @default.
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• W2785015766 doi "https://doi.org/10.1021/acs.cgd.7b01645" @default.
• W2785015766 hasPublicationYear "2018" @default.
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