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• W2785243417 endingPage "1591" @default.
• W2785243417 startingPage "1588" @default.
• W2785243417 abstract "Partial substitution of Ce4+ by Nb5+ is possible in CeO2 by coinclusion of Na+ to balance the charge, via hydrothermal synthesis in sodium hydroxide solution. Pair distribution function analysis using reverse Monte Carlo refinement reveals that the small pentavalent substituent resides in irregular coordination positions in an average fluorite lattice, displaced away from the ideal cubic coordination toward four oxygens. This results in under-coordinated oxygen, which explains significantly enhanced oxygen storage capacity of the materials of relevance to redox catalysis used in energy and environmental applications." @default.
• W2785243417 created "2018-02-02" @default.
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• W2785243417 date "2018-01-24" @default.
• W2785243417 modified "2023-09-23" @default.
• W2785243417 title "Pair Distribution Function Analysis of Structural Disorder by Nb⁵⁺ Inclusion in Ceria: Evidence for Enhanced Oxygen Storage Capacity from Under-Coordinated Oxide" @default.
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• W2785243417 doi "https://doi.org/10.1021/jacs.7b12421" @default.
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• W2785243417 hasPublicationYear "2018" @default.
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