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• W2785451777 abstract "NMR chemical profiling of a Laurenciella sp. using a computerized method developed in our laboratory resulted in the identification of five new compounds (1–5) and 17 known compounds, among which 3-(E)-laurenyne represented by far the most abundant metabolite. Compounds 1 to 5 were isolated and fully characterized by detailed spectroscopic analysis. The absolute configuration and structural features of compound 1 were determined by single-crystal X-ray diffraction analysis. Compounds 1 to 4 are 12-membered cyclic ether acetogenins that are present in solution as interconverting conformers exhibiting an (aR) configuration of the bromoallene unit together with an S configuration at C-4. Among these, compound 3 is the first obtusallene derivative with bromine substituents at both the C-7 and C-12 positions. Compound 5 is an acetogenin bearing a [5.5.1]bicyclotridecane ring system. A plausible biosynthetic route to 1–4 is proposed." @default.
• W2785451777 created "2018-02-23" @default.
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• W2785451777 date "2018-01-30" @default.
• W2785451777 modified "2023-10-04" @default.
• W2785451777 title "Halogenated C₁₅ Acetogenin Analogues of Obtusallene III from a <i>Laurenciella</i> sp. Collected in Corsica" @default.
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• W2785451777 doi "https://doi.org/10.1021/acs.jnatprod.7b00706" @default.
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• W2785451777 hasPublicationYear "2018" @default.
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