Matches in SemOpenAlex for { <https://semopenalex.org/work/W2785461137> ?p ?o ?g. }
- W2785461137 endingPage "3051" @default.
- W2785461137 startingPage "3040" @default.
- W2785461137 abstract "The isostructural, two-dimensional metal-organic frameworks (H2NMe2)2M2(Cl2dhbq)3 (M = Ti, V; Cl2dhbqn- = deprotonated 2,5-dichloro-3,6-dihydroxybenzoquinone) and (H2NMe2)1.5Cr2(dhbq)3 (dhbqn- = deprotonated 2,5-dihydroxybenzoquinone) are synthesized and investigated by spectroscopic, magnetic, and electrochemical methods. The three frameworks exhibit substantial differences in their electronic structures, and the bulk electronic conductivities of these phases correlate with the extent of delocalization observed via UV-vis-NIR and IR spectroscopies. Notably, substantial metal-ligand covalency in the vanadium phase results in the quenching of ligand-based spins, the observation of simultaneous metal- and ligand-based redox processes, and a high electronic conductivity of 0.45 S/cm. A molecular orbital analysis of these materials and a previously reported iron congener suggests that the differences in conductivity can be explained by correlating the metal-ligand energy alignment with the energy of intervalence charge-transfer transitions, which should determine the barrier to charge hopping in the mixed-valence frameworks." @default.
- W2785461137 created "2018-02-23" @default.
- W2785461137 creator A5025156552 @default.
- W2785461137 creator A5028972772 @default.
- W2785461137 creator A5042591801 @default.
- W2785461137 date "2018-02-15" @default.
- W2785461137 modified "2023-10-16" @default.
- W2785461137 title "Control of Electronic Structure and Conductivity in Two-Dimensional Metal–Semiquinoid Frameworks of Titanium, Vanadium, and Chromium" @default.
- W2785461137 cites W1837863733 @default.
- W2785461137 cites W1965373097 @default.
- W2785461137 cites W1972147096 @default.
- W2785461137 cites W1975628435 @default.
- W2785461137 cites W1976849993 @default.
- W2785461137 cites W1977165798 @default.
- W2785461137 cites W1978604265 @default.
- W2785461137 cites W1978729528 @default.
- W2785461137 cites W1979681627 @default.
- W2785461137 cites W1980203429 @default.
- W2785461137 cites W1982464245 @default.
- W2785461137 cites W1983468448 @default.
- W2785461137 cites W1983727115 @default.
- W2785461137 cites W1990143227 @default.
- W2785461137 cites W1990693207 @default.
- W2785461137 cites W1997030277 @default.
- W2785461137 cites W2002576040 @default.
- W2785461137 cites W2003675302 @default.
- W2785461137 cites W2004317657 @default.
- W2785461137 cites W2009813721 @default.
- W2785461137 cites W2010300954 @default.
- W2785461137 cites W2010593883 @default.
- W2785461137 cites W2014140141 @default.
- W2785461137 cites W2014511551 @default.
- W2785461137 cites W2017631832 @default.
- W2785461137 cites W2020418231 @default.
- W2785461137 cites W2024955761 @default.
- W2785461137 cites W2024962351 @default.
- W2785461137 cites W2025452585 @default.
- W2785461137 cites W2026386980 @default.
- W2785461137 cites W2030003306 @default.
- W2785461137 cites W2030054392 @default.
- W2785461137 cites W2033227526 @default.
- W2785461137 cites W2040946523 @default.
- W2785461137 cites W2043698546 @default.
- W2785461137 cites W2045462665 @default.
- W2785461137 cites W2046604627 @default.
- W2785461137 cites W2054037184 @default.
- W2785461137 cites W2056573553 @default.
- W2785461137 cites W2063421331 @default.
- W2785461137 cites W2066969355 @default.
- W2785461137 cites W2067211621 @default.
- W2785461137 cites W2068479397 @default.
- W2785461137 cites W2070434644 @default.
- W2785461137 cites W2073152413 @default.
- W2785461137 cites W2073294207 @default.
- W2785461137 cites W2079528923 @default.
- W2785461137 cites W2079975237 @default.
- W2785461137 cites W2087763550 @default.
- W2785461137 cites W2091393784 @default.
- W2785461137 cites W2093710037 @default.
- W2785461137 cites W2094508515 @default.
- W2785461137 cites W2100980024 @default.
- W2785461137 cites W2112307556 @default.
- W2785461137 cites W2131972993 @default.
- W2785461137 cites W2138289499 @default.
- W2785461137 cites W2142171789 @default.
- W2785461137 cites W2156487970 @default.
- W2785461137 cites W2158919083 @default.
- W2785461137 cites W2159519319 @default.
- W2785461137 cites W2171600997 @default.
- W2785461137 cites W2192082872 @default.
- W2785461137 cites W2230127221 @default.
- W2785461137 cites W2236314447 @default.
- W2785461137 cites W2260512632 @default.
- W2785461137 cites W2267990318 @default.
- W2785461137 cites W2292820216 @default.
- W2785461137 cites W2316777255 @default.
- W2785461137 cites W2316976592 @default.
- W2785461137 cites W2331460189 @default.
- W2785461137 cites W2333218752 @default.
- W2785461137 cites W2338529868 @default.
- W2785461137 cites W2491085471 @default.
- W2785461137 cites W2495418065 @default.
- W2785461137 cites W2497007159 @default.
- W2785461137 cites W2551777530 @default.
- W2785461137 cites W2590385466 @default.
- W2785461137 cites W2593205476 @default.
- W2785461137 cites W2593879643 @default.
- W2785461137 cites W2595755924 @default.
- W2785461137 cites W2606318172 @default.
- W2785461137 cites W2735584884 @default.
- W2785461137 cites W2737951914 @default.
- W2785461137 cites W2952863102 @default.
- W2785461137 cites W3212985408 @default.
- W2785461137 cites W4206855549 @default.
- W2785461137 cites W4211133177 @default.
- W2785461137 doi "https://doi.org/10.1021/jacs.7b13510" @default.
- W2785461137 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29400059" @default.
- W2785461137 hasPublicationYear "2018" @default.