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• W2785682743 startingPage "1135" @default.
• W2785682743 abstract "This chapter discusses chiroptical detectors for high-performance liquid chromatography (HPLC) of carbohydrates. Chiroptical detectors are devices that are based upon the three physical phenomena that are peculiar to optically active (chiral) molecules: polarimetry, optical rotatory dispersion (ORD), and circular dichroism (CD). As chiroptic detector technology develops and selectivities and sensitivities are increased, multiple wavelength and even full spectral methods can become practical realities. Polarimetric detection is conceptually a simple measurement of the direction and magnitude of the angle of rotation of a beam of incident linearly polarized light on its transmission through a chiral medium. Dispersion of the angle of rotation with wavelength leads to the production of ORD. While working either alone or in combination with nonselective detectors, chiroptical detectors can be used to confirm molecular stereochemistry to gather structural information, such as linkage isomerism in polymers, and measure the enantiomeric purities of chiral analytes." @default.
• W2785682743 created "2018-02-23" @default.
• W2785682743 creator A5076181316 @default.
• W2785682743 date "2002-01-01" @default.
• W2785682743 modified "2023-09-27" @default.
• W2785682743 title "Chapter 31 Chiroptical detectors for HPLC of carbohydrates" @default.
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• W2785682743 doi "https://doi.org/10.1016/s0301-4770(02)80056-2" @default.
• W2785682743 hasPublicationYear "2002" @default.
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