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- W2786001570 abstract "The energy offset between the electrode Fermi level and organic semiconductor transport levels is a key parameter controlling the charge injection barrier and hence efficiency of organic electronic devices. Here, we systematically explore the effect of in situ oxygen exposure on energetics in n-type conjugated polymer P(NDI2OD-T2) films. The analysis reveals that an interfacial potential step is introduced for a series of P(NDI2OD-T2) electrode contacts, causing a nearly constant downshift of the vacuum level, while the ionization energies versus vacuum level remain constant. These findings are attributed to the establishment of a so-called double-dipole step via motion of charged molecules and will modify the charge injection barriers at electrode contact. We further demonstrate that the same behavior occurs when oxygen interacts with p-type polymer TQ1 films, indicating it is possible to be a universal effect for organic semiconductors." @default.
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- W2786001570 date "2018-02-07" @default.
- W2786001570 modified "2023-09-29" @default.
- W2786001570 title "The Effect of Oxygen Uptake on Charge Injection Barriers in Conjugated Polymer Films" @default.
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- W2786001570 doi "https://doi.org/10.1021/acsami.7b17368" @default.
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