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- W2786352664 abstract "Selected orttho-bromophenols have been studied to determine the effect of the solvents hexane, carbon tetrachloride, chloroform, carbon disulphide and acetonitrile upon the frequencies, half band widths and apparent molecular extinction coefficients of the hydroxyl stretching absorptions. The “intra-bonded”, OH · Br, hydroxyl frequencies undergo smaller solvent shifts than those of the free hydroxyl groupings. The effect of temperature on the hydroxyl stretching absorptions of 2-bromophenol and 2,4-dibromo-6-t-butylphenol in tetrachloroethylene is reported and the hydroxyl stretching absorptions of a number of substituted ortho-bromophenols in ether-carbon tetrachloride mixtures have been measured. The phenolic hydroxyl of ortho-bromophenols shows greater preference for intramolecular (OH · Br) bonding, rather than intermolecular (OH ṫ OEt2) hydrogen bonding. Comparisons are made with a number of 2-alkyl- and 2,6-dialkylphenols and the results discussed." @default.
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- W2786352664 date "1963-02-01" @default.
- W2786352664 modified "2023-09-26" @default.
- W2786352664 title "Infrared studies with substituted orftho-bromophenols—part II" @default.
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- W2786352664 doi "https://doi.org/10.1016/0371-1951(63)80058-2" @default.
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