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- W2786386157 endingPage "623" @default.
- W2786386157 startingPage "618" @default.
- W2786386157 abstract "Treatment of cyclopropaosmapentalene (1) with EtC≡CEt in the presence of AgBF4 gave a new type of polycyclic metallaaromatic complex with a structure containing an sp3 carbon and a β-agostic Os···H–C(sp3) interaction. This result strongly supported our proposed intermediate in the reaction of cyclopropaosmapentalene 1 with alkynes that produced photothermal osmium carbolong complexes. When EtC≡CCOMe was used, the reaction gave a more thermally stable ketone-coordinated complex as the major product. The DFT study indicated that the difference in the two reactions is of thermodynamic origin." @default.
- W2786386157 created "2018-02-23" @default.
- W2786386157 creator A5005062291 @default.
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- W2786386157 creator A5050195786 @default.
- W2786386157 creator A5060283067 @default.
- W2786386157 date "2018-02-09" @default.
- W2786386157 modified "2023-10-14" @default.
- W2786386157 title "Synthesis and Characterization of an Osmapentalene Derivative Containing a β-Agostic Os···H–C(sp<sup>3</sup>) Interaction" @default.
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