Matches in SemOpenAlex for { <https://semopenalex.org/work/W2786454024> ?p ?o ?g. }
- W2786454024 endingPage "800" @default.
- W2786454024 startingPage "791" @default.
- W2786454024 abstract "Immortal copolymerization of epoxides/CO2 using macro-chain-transfer agent (macro-CTA) is a useful method to prepare CO2-based block copolymers for manufacturing high value-added materials. Despite a variety of CO2-based block copolymers that have been reported using distinct macro-CTAs, issues including catalytic activity and blocking efficiency for the immortal polymerization remain superficially understood. Here, we systematically studied the reaction activity and blocking efficiency by using various macro-CTAs (including PPG, PEG, and PS) in the presence of two classical catalyst systems ((BDI)ZnOAc and SalenCoTFA/PPN-TFA). By analysis of the gel permeation chromatograms via mathematical deconvolution, it comes to a conclusion that the size, nature, and ratio of [macro-CTA]/[Cat.] strongly influence the catalytic activity of the reaction and blocking efficiency for the resultant block copolymers. Thin film self-assembly of PS/PPC block copolymers was investigated, and the results were analyzed by SEM to ascertain the impact of blocking efficiency on nanoassembly." @default.
- W2786454024 created "2018-02-23" @default.
- W2786454024 creator A5018918501 @default.
- W2786454024 creator A5020060475 @default.
- W2786454024 creator A5044794520 @default.
- W2786454024 creator A5044828294 @default.
- W2786454024 creator A5046655494 @default.
- W2786454024 creator A5048926918 @default.
- W2786454024 creator A5063368064 @default.
- W2786454024 creator A5073531557 @default.
- W2786454024 creator A5077255739 @default.
- W2786454024 creator A5079977786 @default.
- W2786454024 creator A5081624472 @default.
- W2786454024 date "2018-02-01" @default.
- W2786454024 modified "2023-10-04" @default.
- W2786454024 title "Synthesis of CO<sub>2</sub>-Based Block Copolymers via Chain Transfer Polymerization Using Macroinitiators: Activity, Blocking Efficiency, and Nanostructure" @default.
- W2786454024 cites W1915962847 @default.
- W2786454024 cites W1927730430 @default.
- W2786454024 cites W1965213743 @default.
- W2786454024 cites W1972027918 @default.
- W2786454024 cites W1972954533 @default.
- W2786454024 cites W1973045139 @default.
- W2786454024 cites W1973561663 @default.
- W2786454024 cites W1974603206 @default.
- W2786454024 cites W1974695290 @default.
- W2786454024 cites W1980761928 @default.
- W2786454024 cites W1984258874 @default.
- W2786454024 cites W1985040528 @default.
- W2786454024 cites W1988593925 @default.
- W2786454024 cites W1990480220 @default.
- W2786454024 cites W1991001415 @default.
- W2786454024 cites W1993403734 @default.
- W2786454024 cites W1995762075 @default.
- W2786454024 cites W1996377813 @default.
- W2786454024 cites W2000828353 @default.
- W2786454024 cites W2011887848 @default.
- W2786454024 cites W2016409727 @default.
- W2786454024 cites W2016670499 @default.
- W2786454024 cites W2033823517 @default.
- W2786454024 cites W2055536680 @default.
- W2786454024 cites W2055621849 @default.
- W2786454024 cites W2056945293 @default.
- W2786454024 cites W2060573689 @default.
- W2786454024 cites W2065958686 @default.
- W2786454024 cites W2071105954 @default.
- W2786454024 cites W2074515548 @default.
- W2786454024 cites W2077512354 @default.
- W2786454024 cites W2082882995 @default.
- W2786454024 cites W2085881347 @default.
- W2786454024 cites W2090708418 @default.
- W2786454024 cites W2103857876 @default.
- W2786454024 cites W2148615617 @default.
- W2786454024 cites W2149159659 @default.
- W2786454024 cites W2153222976 @default.
- W2786454024 cites W2155668545 @default.
- W2786454024 cites W2158036121 @default.
- W2786454024 cites W2160637656 @default.
- W2786454024 cites W2161652710 @default.
- W2786454024 cites W2162569538 @default.
- W2786454024 cites W2163986861 @default.
- W2786454024 cites W2168009396 @default.
- W2786454024 cites W2168475161 @default.
- W2786454024 cites W2236926437 @default.
- W2786454024 cites W2273058918 @default.
- W2786454024 cites W2280101999 @default.
- W2786454024 cites W2296303080 @default.
- W2786454024 cites W2309286881 @default.
- W2786454024 cites W2317807208 @default.
- W2786454024 cites W2321432509 @default.
- W2786454024 cites W2322039042 @default.
- W2786454024 cites W2324471852 @default.
- W2786454024 cites W2326105557 @default.
- W2786454024 cites W2327463193 @default.
- W2786454024 cites W2330726269 @default.
- W2786454024 cites W2330745941 @default.
- W2786454024 cites W2483057761 @default.
- W2786454024 cites W2519973688 @default.
- W2786454024 cites W2568763441 @default.
- W2786454024 cites W2586994075 @default.
- W2786454024 cites W2607863303 @default.
- W2786454024 cites W2615067289 @default.
- W2786454024 cites W2732008537 @default.
- W2786454024 cites W2951399512 @default.
- W2786454024 doi "https://doi.org/10.1021/acs.macromol.7b02231" @default.
- W2786454024 hasPublicationYear "2018" @default.
- W2786454024 type Work @default.
- W2786454024 sameAs 2786454024 @default.
- W2786454024 citedByCount "30" @default.
- W2786454024 countsByYear W27864540242018 @default.
- W2786454024 countsByYear W27864540242019 @default.
- W2786454024 countsByYear W27864540242020 @default.
- W2786454024 countsByYear W27864540242021 @default.
- W2786454024 countsByYear W27864540242022 @default.
- W2786454024 countsByYear W27864540242023 @default.
- W2786454024 crossrefType "journal-article" @default.
- W2786454024 hasAuthorship W2786454024A5018918501 @default.
- W2786454024 hasAuthorship W2786454024A5020060475 @default.
- W2786454024 hasAuthorship W2786454024A5044794520 @default.