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- W2786464381 abstract "The hydrolysis of phosphonothioates with a binaphthyl group afforded the first example of O-(2'-hydroxy)binaphthyl phosphonothioic acids in good to high yields and >95:5 diastereoselectivity. The reaction proceeds via an axis-to-center chirality-transfer reaction. The ability of these acids to act as chiral molecular auxiliaries was demonstrated by using them as optically active ligands for the asymmetric ethylation of benzaldehyde and as a chiral discriminating agent for chiral aliphatic amines." @default.
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- W2786464381 date "2018-02-12" @default.
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- W2786464381 title "Hydrolysis of Phosphonothioates with a Binaphthyl Group: <i>P</i>-Stereogenic <i>O</i>-Binaphthyl Phosphonothioic Acids and Their Use as Optically Active Ligands and Chiral Discriminating Agents" @default.
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- W2786464381 doi "https://doi.org/10.1021/acs.orglett.8b00147" @default.
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