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• W2787309020 startingPage "3177" @default.
• W2787309020 abstract "An enantioselective α-amination of esters by a Lewis base/copper(I) cooperative catalysis strategy has been developed. The transient chiral C1-ammonium enolate generated from pentafluorophenyl ester and nucleophilic Lewis base is nicely compatible with the copper intermediate formed from N, N-di- t-butyldiaziridinone and Cu(I) to allow for high levels of stereochemical control. The cooperative catalytic reaction leads to a diverse set of highly enantioenriched hydantoins in good yields with excellent enantioselectivities (90-99% ee)." @default.
• W2787309020 created "2018-02-23" @default.
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• W2787309020 date "2018-01-29" @default.
• W2787309020 modified "2023-10-18" @default.
• W2787309020 title "Lewis Base/Copper Cooperatively Catalyzed Asymmetric α-Amination of Esters with Diaziridinone" @default.
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• W2787309020 doi "https://doi.org/10.1021/jacs.7b12628" @default.
• W2787309020 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29377683" @default.
• W2787309020 hasPublicationYear "2018" @default.
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