Matches in SemOpenAlex for { <https://semopenalex.org/work/W2787496553> ?p ?o ?g. }
- W2787496553 endingPage "1896" @default.
- W2787496553 startingPage "1889" @default.
- W2787496553 abstract "We report here the synthesis and thorough characterization of a new family of alkylbiguanides and alkylbiguanidium chlorides by 1H and 13C NMR and X-ray diffraction. Their critical micelle concentration was first determined by surface tension measurements. Hexylbiguanide was then studied as a surfactant in the micellar Suzuki-Miyaura cross-coupling reaction. The unexpected low reactivity of the system at high Pd/hexylbiguanide ratios was due to the change of the size and the shape of the aggregates, observed by transmission electron microscopy. The best catalytic activity was obtained for a 1:1 Pd/hexylbiguanide ratio for which the micellar conditions were conserved. Better results were obtained for several substrates, when compared to those previously obtained with metformin under the same reaction conditions. Higher yields and a better recyclability were obtained under micellar conditions with hexylbiguanide." @default.
- W2787496553 created "2018-02-23" @default.
- W2787496553 creator A5006672097 @default.
- W2787496553 creator A5082544680 @default.
- W2787496553 date "2018-02-13" @default.
- W2787496553 modified "2023-10-16" @default.
- W2787496553 title "Synthesis and Characterization of Biguanide and Biguanidium Surfactants for Efficient and Recyclable Application in the Suzuki–Miyaura Reaction" @default.
- W2787496553 cites W1964150526 @default.
- W2787496553 cites W1972894556 @default.
- W2787496553 cites W1995610640 @default.
- W2787496553 cites W2007476662 @default.
- W2787496553 cites W2015156141 @default.
- W2787496553 cites W2015369681 @default.
- W2787496553 cites W2023967640 @default.
- W2787496553 cites W2027739628 @default.
- W2787496553 cites W2038560345 @default.
- W2787496553 cites W2059403154 @default.
- W2787496553 cites W2061261695 @default.
- W2787496553 cites W2065239095 @default.
- W2787496553 cites W2065359280 @default.
- W2787496553 cites W2068741401 @default.
- W2787496553 cites W2069922427 @default.
- W2787496553 cites W2090662192 @default.
- W2787496553 cites W2135118928 @default.
- W2787496553 cites W2137076989 @default.
- W2787496553 cites W2161581988 @default.
- W2787496553 cites W2217790226 @default.
- W2787496553 cites W2261110271 @default.
- W2787496553 cites W2468694810 @default.
- W2787496553 cites W2507347820 @default.
- W2787496553 cites W2507376058 @default.
- W2787496553 cites W2605128347 @default.
- W2787496553 cites W2605775861 @default.
- W2787496553 cites W2609658274 @default.
- W2787496553 cites W2737659718 @default.
- W2787496553 cites W2759305576 @default.
- W2787496553 cites W2760663104 @default.
- W2787496553 cites W2762598980 @default.
- W2787496553 cites W2765174018 @default.
- W2787496553 cites W2770328963 @default.
- W2787496553 cites W2774940996 @default.
- W2787496553 cites W2784012052 @default.
- W2787496553 cites W289384582 @default.
- W2787496553 cites W2902941920 @default.
- W2787496553 cites W2949313397 @default.
- W2787496553 cites W2952048273 @default.
- W2787496553 cites W2953119370 @default.
- W2787496553 doi "https://doi.org/10.1021/acsomega.7b01962" @default.
- W2787496553 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6641416" @default.
- W2787496553 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31458501" @default.
- W2787496553 hasPublicationYear "2018" @default.
- W2787496553 type Work @default.
- W2787496553 sameAs 2787496553 @default.
- W2787496553 citedByCount "13" @default.
- W2787496553 countsByYear W27874965532018 @default.
- W2787496553 countsByYear W27874965532020 @default.
- W2787496553 countsByYear W27874965532021 @default.
- W2787496553 countsByYear W27874965532022 @default.
- W2787496553 crossrefType "journal-article" @default.
- W2787496553 hasAuthorship W2787496553A5006672097 @default.
- W2787496553 hasAuthorship W2787496553A5082544680 @default.
- W2787496553 hasBestOaLocation W27874965531 @default.
- W2787496553 hasConcept C11268172 @default.
- W2787496553 hasConcept C121332964 @default.
- W2787496553 hasConcept C127413603 @default.
- W2787496553 hasConcept C134018914 @default.
- W2787496553 hasConcept C13965031 @default.
- W2787496553 hasConcept C142724271 @default.
- W2787496553 hasConcept C146088050 @default.
- W2787496553 hasConcept C161790260 @default.
- W2787496553 hasConcept C171250308 @default.
- W2787496553 hasConcept C178790620 @default.
- W2787496553 hasConcept C184651966 @default.
- W2787496553 hasConcept C185592680 @default.
- W2787496553 hasConcept C192562407 @default.
- W2787496553 hasConcept C204787440 @default.
- W2787496553 hasConcept C21951064 @default.
- W2787496553 hasConcept C2776910235 @default.
- W2787496553 hasConcept C2777688063 @default.
- W2787496553 hasConcept C2780323712 @default.
- W2787496553 hasConcept C2780841128 @default.
- W2787496553 hasConcept C42360764 @default.
- W2787496553 hasConcept C48424934 @default.
- W2787496553 hasConcept C55493867 @default.
- W2787496553 hasConcept C555293320 @default.
- W2787496553 hasConcept C58226133 @default.
- W2787496553 hasConcept C62520636 @default.
- W2787496553 hasConcept C64237528 @default.
- W2787496553 hasConcept C71924100 @default.
- W2787496553 hasConcept C8892853 @default.
- W2787496553 hasConceptScore W2787496553C11268172 @default.
- W2787496553 hasConceptScore W2787496553C121332964 @default.
- W2787496553 hasConceptScore W2787496553C127413603 @default.
- W2787496553 hasConceptScore W2787496553C134018914 @default.
- W2787496553 hasConceptScore W2787496553C13965031 @default.
- W2787496553 hasConceptScore W2787496553C142724271 @default.
- W2787496553 hasConceptScore W2787496553C146088050 @default.
- W2787496553 hasConceptScore W2787496553C161790260 @default.