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- W2788525461 abstract "Metal-organic contacts are keys to define the functionalities of hybrid structures, but orbital hybridization at interfaces has made rationalizing their behavior a challenging task. Here, we examined Fe/C60 and Ni/C60 bilayers with X-ray absorption spectra to study the nature of orbital hybridization and the possible correlation with metal penetration. Depositing Fe or Ni on C60 films of sub-nanometer thickness to emulate interfaces, we found that both bilayers show evidence of not only d-π hybridization and metal penetration but also a deeper Ni penetration. The carbon K-edge spectra recorded from C60 films indicate that the deeper Ni penetration is accompanied by a larger donation of electrons from Ni to C60. This finding of hybridization-modulated metal penetration is somewhat counterintuitive but is consistent with a scenario of metal-C60 hybridization competing with metal-metal aggregation. A stronger Ni-C60 hybridization could result in smaller Ni clusters and a greater probability of penetration through the interstitial space between C60 molecules. We conclude that metal penetration can be regulated with orbital hybridization between metal and C60." @default.
- W2788525461 created "2018-03-06" @default.
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- W2788525461 date "2018-02-19" @default.
- W2788525461 modified "2023-09-27" @default.
- W2788525461 title "Hybridization regulated metal penetration at transition metal-organic semiconductor contacts" @default.
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- W2788525461 doi "https://doi.org/10.1063/1.5004760" @default.
- W2788525461 hasPublicationYear "2018" @default.
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