FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2788574851> ?p ?o ?g. }

• W2788574851 endingPage "30" @default.
• W2788574851 startingPage "25" @default.
• W2788574851 abstract "In this work, we examine, using molecular simulation, the liquid-vapor phase equilibria and atomic-level structure of an ethylene-expanded mixture of methanol, water and hydrogen peroxide as functions of temperature and pressure. The motivation for this study is a recently proposed catalytic process for the epoxidation of ethylene to ethylene oxide in Nb-doped silica nanopores [J. Catal. 336 75 (2016)], where the solvent (methanol) is expanded by the reactant (ethylene) in the presence of the oxidant (hydrogen peroxide in water). Optimal tuning of the reaction conditions can be greatly facilitated by detailed information as to the phase equilibrium and local structure (e.g., hydrogen bonding) of this quaternary mixture. In particular, we focus on the solubility of ethylene in this system as a function of water content. We compare this quaternary system to the recently studied ethylene/methanol/water ternary mixture [Fluid Phase Equilib. 429 275 (2016)]. One major conclusion of this work is that for solutions in which the methanol to water/hydrogen peroxide ratio is greater than 50%, the solubility of ethylene in the quaternary mixture is identical within the statistical error to that of a corresponding ternary mixture, in which hydrogen peroxide is replaced by water. Given that these methanol-rich systems are precisely those of most utility in the epoxidation process, this observation greatly simplifies the phase-equilibrium analysis." @default.
• W2788574851 created "2018-03-06" @default.
• W2788574851 creator A5033051862 @default.
• W2788574851 creator A5050379603 @default.
• W2788574851 date "2018-04-01" @default.
• W2788574851 modified "2023-10-14" @default.
• W2788574851 title "Phase equilibrium of a quaternary system: Methanol, ethylene, water and hydrogen peroxide" @default.
• W2788574851 cites W1978056830 @default.
• W2788574851 cites W1985053924 @default.
• W2788574851 cites W1991794210 @default.
• W2788574851 cites W2004610182 @default.
• W2788574851 cites W2010587930 @default.
• W2788574851 cites W2011111952 @default.
• W2788574851 cites W2017196167 @default.
• W2788574851 cites W2019465613 @default.
• W2788574851 cites W2025074821 @default.
• W2788574851 cites W2027259443 @default.
• W2788574851 cites W2031008196 @default.
• W2788574851 cites W2044252394 @default.
• W2788574851 cites W2049475242 @default.
• W2788574851 cites W2056157932 @default.
• W2788574851 cites W2058107419 @default.
• W2788574851 cites W2164815849 @default.
• W2788574851 cites W2201981543 @default.
• W2788574851 cites W2264172610 @default.
• W2788574851 cites W2286449138 @default.
• W2788574851 cites W2505177498 @default.
• W2788574851 cites W2512480372 @default.
• W2788574851 cites W2585426041 @default.
• W2788574851 cites W2608747371 @default.
• W2788574851 doi "https://doi.org/10.1016/j.fluid.2018.01.010" @default.
• W2788574851 hasPublicationYear "2018" @default.
• W2788574851 type Work @default.
• W2788574851 sameAs 2788574851 @default.
• W2788574851 citedByCount "1" @default.
• W2788574851 countsByYear W27885748512023 @default.
• W2788574851 crossrefType "journal-article" @default.
• W2788574851 hasAuthorship W2788574851A5033051862 @default.
• W2788574851 hasAuthorship W2788574851A5050379603 @default.
• W2788574851 hasConcept C122247533 @default.
• W2788574851 hasConcept C127413603 @default.
• W2788574851 hasConcept C155574463 @default.
• W2788574851 hasConcept C15920480 @default.
• W2788574851 hasConcept C161790260 @default.
• W2788574851 hasConcept C178790620 @default.
• W2788574851 hasConcept C179104552 @default.
• W2788574851 hasConcept C185592680 @default.
• W2788574851 hasConcept C199360897 @default.
• W2788574851 hasConcept C2777801237 @default.
• W2788574851 hasConcept C2778597550 @default.
• W2788574851 hasConcept C2779607525 @default.
• W2788574851 hasConcept C2780471494 @default.
• W2788574851 hasConcept C41008148 @default.
• W2788574851 hasConcept C42360764 @default.
• W2788574851 hasConcept C44280652 @default.
• W2788574851 hasConcept C512968161 @default.
• W2788574851 hasConcept C521977710 @default.
• W2788574851 hasConcept C533411734 @default.
• W2788574851 hasConcept C64452783 @default.
• W2788574851 hasConceptScore W2788574851C122247533 @default.
• W2788574851 hasConceptScore W2788574851C127413603 @default.
• W2788574851 hasConceptScore W2788574851C155574463 @default.
• W2788574851 hasConceptScore W2788574851C15920480 @default.
• W2788574851 hasConceptScore W2788574851C161790260 @default.
• W2788574851 hasConceptScore W2788574851C178790620 @default.
• W2788574851 hasConceptScore W2788574851C179104552 @default.
• W2788574851 hasConceptScore W2788574851C185592680 @default.
• W2788574851 hasConceptScore W2788574851C199360897 @default.
• W2788574851 hasConceptScore W2788574851C2777801237 @default.
• W2788574851 hasConceptScore W2788574851C2778597550 @default.
• W2788574851 hasConceptScore W2788574851C2779607525 @default.
• W2788574851 hasConceptScore W2788574851C2780471494 @default.
• W2788574851 hasConceptScore W2788574851C41008148 @default.
• W2788574851 hasConceptScore W2788574851C42360764 @default.
• W2788574851 hasConceptScore W2788574851C44280652 @default.
• W2788574851 hasConceptScore W2788574851C512968161 @default.
• W2788574851 hasConceptScore W2788574851C521977710 @default.
• W2788574851 hasConceptScore W2788574851C533411734 @default.
• W2788574851 hasConceptScore W2788574851C64452783 @default.
• W2788574851 hasFunder F4320320835 @default.
• W2788574851 hasFunder F4320335353 @default.
• W2788574851 hasLocation W27885748511 @default.
• W2788574851 hasOpenAccess W2788574851 @default.
• W2788574851 hasPrimaryLocation W27885748511 @default.
• W2788574851 hasRelatedWork W1526871137 @default.
• W2788574851 hasRelatedWork W1972780478 @default.
• W2788574851 hasRelatedWork W1993554690 @default.
• W2788574851 hasRelatedWork W2063857146 @default.
• W2788574851 hasRelatedWork W2072428022 @default.
• W2788574851 hasRelatedWork W2128885786 @default.
• W2788574851 hasRelatedWork W2234406417 @default.
• W2788574851 hasRelatedWork W2560832559 @default.
• W2788574851 hasRelatedWork W3109205869 @default.
• W2788574851 hasRelatedWork W3198334085 @default.
• W2788574851 hasVolume "462" @default.
• W2788574851 isParatext "false" @default.
• W2788574851 isRetracted "false" @default.
• W2788574851 magId "2788574851" @default.

• next