FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2788584542> ?p ?o ?g. }

• W2788584542 endingPage "171719" @default.
• W2788584542 startingPage "171719" @default.
• W2788584542 abstract "A thorough analysis of the photophysical properties involved in electronic transitions in excitation–emission spectra of xylene isomers has been carried out using the time-dependent density functional theory (PBEPBE/6-31 + G(d,p)) method. For the first time a structural and spectroscopic investigation to distinguish isomers of xylene, a widespread priority pollutant, was conducted experimentally and theoretically. The fluorescence properties of xylene isomers (sole and mixture (binary and ternary)) in water were studied. The fluorescence peak intensities of xylenes were linearly correlated to concentration, in the order of p -xylene > o -xylene > m -xylene at an excitation/emission wavelength (ex/em) of 260 nm/285 nm for o -, m -xylene and ex/em 265 nm/290 nm for p -xylene at the same concentration. The theoretical excitation/emission wavelengths were at ex/em 247 nm/267 nm, 248 nm/269 nm and 251 nm/307 nm for o -, m - and p -xylene, respectively. The vertical excitation and emission state energies of p -xylene (ex/em 4.94 eV/4.03 eV) were lower and the internal conversion energy difference (0.90 eV) was higher than those of m -xylene (ex/em 5.00 eV/4.60 eV) (0.4 eV) and o -xylene (ex/em 5.02 eV/4.64 eV) (0.377 eV). The order of theoretical emission and oscillator strength (0.0187 > 0.0175 > 0.0339) for p -xylene > o -xylene > m -xylene was observed to be in agreement with the experimental fluorescence intensities. These findings provide a novel fast method to distinguish isomers based on their photophysical properties." @default.
• W2788584542 created "2018-03-06" @default.
• W2788584542 creator A5004908266 @default.
• W2788584542 creator A5018731801 @default.
• W2788584542 creator A5018974271 @default.
• W2788584542 creator A5020088480 @default.
• W2788584542 creator A5025451558 @default.
• W2788584542 creator A5041980453 @default.
• W2788584542 creator A5090815103 @default.
• W2788584542 date "2018-02-01" @default.
• W2788584542 modified "2023-10-12" @default.
• W2788584542 title "Fluorescence and photophysical properties of xylene isomers in water: with experimental and theoretical approaches" @default.
• W2788584542 cites W1043580195 @default.
• W2788584542 cites W1602645704 @default.
• W2788584542 cites W1950657003 @default.
• W2788584542 cites W1965481727 @default.
• W2788584542 cites W1971122381 @default.
• W2788584542 cites W1981368803 @default.
• W2788584542 cites W1984503986 @default.
• W2788584542 cites W1986625458 @default.
• W2788584542 cites W1987027138 @default.
• W2788584542 cites W1987140446 @default.
• W2788584542 cites W1990440930 @default.
• W2788584542 cites W1991219361 @default.
• W2788584542 cites W1994431235 @default.
• W2788584542 cites W2003213735 @default.
• W2788584542 cites W2011319133 @default.
• W2788584542 cites W2011538892 @default.
• W2788584542 cites W2024322856 @default.
• W2788584542 cites W2028065427 @default.
• W2788584542 cites W2038447511 @default.
• W2788584542 cites W2039777710 @default.
• W2788584542 cites W2048127428 @default.
• W2788584542 cites W2054704030 @default.
• W2788584542 cites W2059834902 @default.
• W2788584542 cites W2083920714 @default.
• W2788584542 cites W2108344169 @default.
• W2788584542 cites W2158788902 @default.
• W2788584542 cites W2182640634 @default.
• W2788584542 cites W2208828712 @default.
• W2788584542 cites W2258356825 @default.
• W2788584542 cites W2273519772 @default.
• W2788584542 cites W2290512913 @default.
• W2788584542 cites W2296294370 @default.
• W2788584542 cites W2323569896 @default.
• W2788584542 cites W2337516837 @default.
• W2788584542 cites W2344167930 @default.
• W2788584542 cites W2381103086 @default.
• W2788584542 cites W2394857622 @default.
• W2788584542 cites W2410240336 @default.
• W2788584542 cites W2425459573 @default.
• W2788584542 cites W2440310718 @default.
• W2788584542 cites W2482639755 @default.
• W2788584542 cites W2484199773 @default.
• W2788584542 cites W2523247764 @default.
• W2788584542 cites W2540230319 @default.
• W2788584542 cites W2592166782 @default.
• W2788584542 cites W2755657472 @default.
• W2788584542 cites W343387047 @default.
• W2788584542 cites W977381312 @default.
• W2788584542 doi "https://doi.org/10.1098/rsos.171719" @default.
• W2788584542 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5830770" @default.
• W2788584542 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29515881" @default.
• W2788584542 hasPublicationYear "2018" @default.
• W2788584542 type Work @default.
• W2788584542 sameAs 2788584542 @default.
• W2788584542 citedByCount "13" @default.
• W2788584542 countsByYear W27885845422018 @default.
• W2788584542 countsByYear W27885845422020 @default.
• W2788584542 countsByYear W27885845422021 @default.
• W2788584542 countsByYear W27885845422022 @default.
• W2788584542 countsByYear W27885845422023 @default.
• W2788584542 crossrefType "journal-article" @default.
• W2788584542 hasAuthorship W2788584542A5004908266 @default.
• W2788584542 hasAuthorship W2788584542A5018731801 @default.
• W2788584542 hasAuthorship W2788584542A5018974271 @default.
• W2788584542 hasAuthorship W2788584542A5020088480 @default.
• W2788584542 hasAuthorship W2788584542A5025451558 @default.
• W2788584542 hasAuthorship W2788584542A5041980453 @default.
• W2788584542 hasAuthorship W2788584542A5090815103 @default.
• W2788584542 hasBestOaLocation W27885845421 @default.
• W2788584542 hasConcept C113196181 @default.
• W2788584542 hasConcept C120665830 @default.
• W2788584542 hasConcept C121332964 @default.
• W2788584542 hasConcept C178790620 @default.
• W2788584542 hasConcept C185592680 @default.
• W2788584542 hasConcept C192562407 @default.
• W2788584542 hasConcept C199360897 @default.
• W2788584542 hasConcept C2776396718 @default.
• W2788584542 hasConcept C2777691172 @default.
• W2788584542 hasConcept C2778142098 @default.
• W2788584542 hasConcept C2779896714 @default.
• W2788584542 hasConcept C2780963519 @default.
• W2788584542 hasConcept C2993001476 @default.
• W2788584542 hasConcept C41008148 @default.
• W2788584542 hasConcept C49040817 @default.
• W2788584542 hasConcept C62520636 @default.
• W2788584542 hasConcept C6260449 @default.

• next