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- W2788749553 abstract "A stereoselective synthesis of the dibenzocyclooctadiene lignan core of the natural product schisandrene is described. Starting from readily available gallic acid, the synthetic strategy involves Suzuki–Miyaura cross-coupling, Stille reaction, and ring-closing metathesis (RCM) in the reaction sequence. The required asymmetric center at C-7′ was established by an asymmetric reduction of a keto compound using the Corey–Bakshi–Shibata (CBS) catalyst. In our approach, the eight-membered ring was achieved by RCM for the first time." @default.
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- W2788749553 date "2018-02-19" @default.
- W2788749553 modified "2023-10-18" @default.
- W2788749553 title "Towards the Total Synthesis of Schisandrene: Stereoselective Synthesis of the Dibenzocyclooctadiene Lignan Core" @default.
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- W2788749553 doi "https://doi.org/10.1055/s-0036-1591539" @default.
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