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- W2788794810 endingPage "71" @default.
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- W2788794810 abstract "Carbodicarbenes are a special class of bisylidic CL2 compounds, the so-called carbones. Carbones are divalent carbon compounds, in which a four-electron carbon atom in the oxidation state of zero is bound by two σ-donor ligands L via donor-acceptor interactions, resulting in the formulation L→C(0)←L. In carbodicarbenes (CDCs), the L ligand is a N-heterocyclic carbene (NHC) or any other singlet carbene species. Comparable to “classical” bisylides, CDCs possess two lone pairs of electrons at the central carbon atom, thus making them stronger σ-donors than conventional carbenes like NHCs. These unusual donor properties make CDCs unique and highly potent ligands for transition metals and catalysis. This chapter summarizes the exciting developments of the last 10 years in CDC chemistry. A concise overview of this new class of carbone compounds is given by summarizing the synthesis of different CDC frameworks as well as their application in transition metal chemistry and homogenous catalysis." @default.
- W2788794810 created "2018-03-06" @default.
- W2788794810 creator A5007538344 @default.
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- W2788794810 date "2018-01-01" @default.
- W2788794810 modified "2023-10-16" @default.
- W2788794810 title "Synthesis and Structure of Carbodicarbenes and Their Application in Catalysis" @default.
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- W2788794810 doi "https://doi.org/10.1007/430_2017_20" @default.
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