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- W2789243473 abstract "A novel 1, 8-naphthalimide-based derivative, named as (E)-6-(2-((1H-pyrrol-2-yl)methylene)hydrazinyl)-2-(2-hydroxyethyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione (HHBD), was synthesized via facile condensation and substitution reactions. It showed high sensitivity and selectivity to Cu2+ in CH3CNH2O (v/v = 3:7, pH = 7.0) solution, and the hypsochromic shift of the absorption band & the enhancement of the fluorescence emission intensity were distinct for the detection of Cu2+ even in the presence of other competitive metal ions, such as Ag+, Al3+, Ca2+, Co2+, Cr3+, Fe2+, Fe3+, K+, Li+, Mg2+, Na+, Ni3+, Zn2+. The binding stoichiometry between HHBD and Cu2+ was calculated from Job’s plot and the complexation mechanism was explored by 1H NMR and FTIR spectrophotometry. Furthermore, HHBD binding capability with Cu2+ was further demonstrated using DFT calculations. The probe was applied successfully in real water samples assay. Strip papers were also designed and used to detect various concentrations of Cu2+ aqueous solution, whose color change showed their potential application for on-site detection of Cu2+ in pollution water." @default.
- W2789243473 created "2018-03-29" @default.
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- W2789243473 date "2018-07-01" @default.
- W2789243473 modified "2023-10-17" @default.
- W2789243473 title "A sensitive and selective probe for visual detection of Cu2+ based on 1, 8-naphthalimidederivative" @default.
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- W2789243473 doi "https://doi.org/10.1016/j.snb.2018.03.050" @default.
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