Matches in SemOpenAlex for { <https://semopenalex.org/work/W2789479275> ?p ?o ?g. }
- W2789479275 endingPage "6602" @default.
- W2789479275 startingPage "6594" @default.
- W2789479275 abstract "The SO42−/MxOy (M = Cu, Co, Fe) catalysts were prepared and applied to hydrogen production from methanolysis of sodium borohydride for the first time. The morphologies and properties of the as-prepared catalysts were characterized by XRD, BET, FT-IR, TEM and SEM-EDX techniques. Under our experimental conditions, SO42−/CuO exhibits much higher catalytic activity than those of SO42−/CoO and SO42−/Fe2O3 catalysts and follows the order of SO42−/CuO > SO42−/CoO > SO42−/Fe2O3, which is opposite to order of BET surface area, implying that the methanolysis of sodium borohydride is not a structure-sensitive reaction. It can be inferred that both acidic and metallic sites are responsible for the high catalytic performance of the SO42−/MxOy catalysts towards NaBH4 methanolysis. In addition, the effects of the concentrations of NaBH4 and methanol, catalyst dosage, and reaction temperature on the hydrogen generation rate have been investigated using SO42−/CuO as catalyst. The SO42−/CuO-catalyzed methanolysis reaction follows a power law, i.e. r = A·exp (−13135/RT)·[NaBH4]1.01·[CH3OH]1.60·[Catalyst]0.52. The apparent activation energy was calculated to be 13.13 kJ/mol." @default.
- W2789479275 created "2018-03-29" @default.
- W2789479275 creator A5002616243 @default.
- W2789479275 creator A5017471501 @default.
- W2789479275 creator A5036594926 @default.
- W2789479275 creator A5038448493 @default.
- W2789479275 creator A5061777151 @default.
- W2789479275 creator A5091812681 @default.
- W2789479275 date "2018-03-01" @default.
- W2789479275 modified "2023-10-13" @default.
- W2789479275 title "Efficient catalytic properties of SO42−/M O (M = Cu, Co, Fe) catalysts for hydrogen generation by methanolysis of sodium borohydride" @default.
- W2789479275 cites W1981175378 @default.
- W2789479275 cites W1990168229 @default.
- W2789479275 cites W1996431504 @default.
- W2789479275 cites W2004717985 @default.
- W2789479275 cites W2005779560 @default.
- W2789479275 cites W2025688142 @default.
- W2789479275 cites W2026529687 @default.
- W2789479275 cites W2038496420 @default.
- W2789479275 cites W2042494170 @default.
- W2789479275 cites W2049581736 @default.
- W2789479275 cites W2052989605 @default.
- W2789479275 cites W2061780107 @default.
- W2789479275 cites W2064680246 @default.
- W2789479275 cites W2068066409 @default.
- W2789479275 cites W2076248566 @default.
- W2789479275 cites W2076599092 @default.
- W2789479275 cites W2077909932 @default.
- W2789479275 cites W2090075026 @default.
- W2789479275 cites W2097332196 @default.
- W2789479275 cites W2101315213 @default.
- W2789479275 cites W2141621806 @default.
- W2789479275 cites W2192865664 @default.
- W2789479275 cites W2472102215 @default.
- W2789479275 cites W2515788699 @default.
- W2789479275 cites W2518673663 @default.
- W2789479275 cites W2520071033 @default.
- W2789479275 cites W2529812248 @default.
- W2789479275 cites W2530672636 @default.
- W2789479275 cites W2534705832 @default.
- W2789479275 cites W2542512130 @default.
- W2789479275 cites W2555368354 @default.
- W2789479275 cites W2563753602 @default.
- W2789479275 cites W2567544512 @default.
- W2789479275 cites W2592564344 @default.
- W2789479275 cites W2600531609 @default.
- W2789479275 cites W286567672 @default.
- W2789479275 cites W2061361805 @default.
- W2789479275 doi "https://doi.org/10.1016/j.ijhydene.2018.02.074" @default.
- W2789479275 hasPublicationYear "2018" @default.
- W2789479275 type Work @default.
- W2789479275 sameAs 2789479275 @default.
- W2789479275 citedByCount "37" @default.
- W2789479275 countsByYear W27894792752018 @default.
- W2789479275 countsByYear W27894792752019 @default.
- W2789479275 countsByYear W27894792752020 @default.
- W2789479275 countsByYear W27894792752021 @default.
- W2789479275 countsByYear W27894792752022 @default.
- W2789479275 countsByYear W27894792752023 @default.
- W2789479275 crossrefType "journal-article" @default.
- W2789479275 hasAuthorship W2789479275A5002616243 @default.
- W2789479275 hasAuthorship W2789479275A5017471501 @default.
- W2789479275 hasAuthorship W2789479275A5036594926 @default.
- W2789479275 hasAuthorship W2789479275A5038448493 @default.
- W2789479275 hasAuthorship W2789479275A5061777151 @default.
- W2789479275 hasAuthorship W2789479275A5091812681 @default.
- W2789479275 hasConcept C121332964 @default.
- W2789479275 hasConcept C135502975 @default.
- W2789479275 hasConcept C13965031 @default.
- W2789479275 hasConcept C147789679 @default.
- W2789479275 hasConcept C148898269 @default.
- W2789479275 hasConcept C161790260 @default.
- W2789479275 hasConcept C178790620 @default.
- W2789479275 hasConcept C179104552 @default.
- W2789479275 hasConcept C185592680 @default.
- W2789479275 hasConcept C202189072 @default.
- W2789479275 hasConcept C2779607525 @default.
- W2789479275 hasConcept C2780048404 @default.
- W2789479275 hasConcept C27923307 @default.
- W2789479275 hasConcept C512968161 @default.
- W2789479275 hasConcept C537181965 @default.
- W2789479275 hasConcept C62520636 @default.
- W2789479275 hasConcept C93391505 @default.
- W2789479275 hasConcept C95121573 @default.
- W2789479275 hasConceptScore W2789479275C121332964 @default.
- W2789479275 hasConceptScore W2789479275C135502975 @default.
- W2789479275 hasConceptScore W2789479275C13965031 @default.
- W2789479275 hasConceptScore W2789479275C147789679 @default.
- W2789479275 hasConceptScore W2789479275C148898269 @default.
- W2789479275 hasConceptScore W2789479275C161790260 @default.
- W2789479275 hasConceptScore W2789479275C178790620 @default.
- W2789479275 hasConceptScore W2789479275C179104552 @default.
- W2789479275 hasConceptScore W2789479275C185592680 @default.
- W2789479275 hasConceptScore W2789479275C202189072 @default.
- W2789479275 hasConceptScore W2789479275C2779607525 @default.
- W2789479275 hasConceptScore W2789479275C2780048404 @default.
- W2789479275 hasConceptScore W2789479275C27923307 @default.
- W2789479275 hasConceptScore W2789479275C512968161 @default.