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• W2789723897 abstract "This work provides a scheme to investigate the site occupancy and the luminescence properties of lanthanide ions in BaY2Si3O10. The Rietveld refinement of the samples indicates that the lanthanide ions preferably occupy the Y3+ sites in BaY2Si3O10. It is confirmed that valence state of lanthanide ions is stable at +3 in all doping samples. The site-dependent spectroscopic properties of Ce3+ and Eu3+ are studied in VUV–UV–vis spectral region at low temperatures, and the polarization effect on Ce3+ luminescence decay is evaluated. The results indicate that the lanthanide ions experience the similar polarization effect when substituting the Y3+ sites in BaY2Si3O10. The Stokes shift of Ce3+ luminescence becomes larger as Ce3+ doping content increases. Eu3+ f–f line-shape change has not been observed in the spectra as Eu3+ content increases. It demonstrates that the change of the electrostatic binding effect in the lattice has little effect on the ligand polarization of the central lanthanide ion. Finally, a m..." @default.
• W2789723897 created "2018-03-29" @default.
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• W2789723897 date "2018-03-01" @default.
• W2789723897 modified "2023-10-16" @default.
• W2789723897 title "Site Occupancy and VUV–UV–Vis Photoluminescence of the Lanthanide Ions in BaY₂Si₃O₁₀" @default.
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• W2789723897 doi "https://doi.org/10.1021/acs.jpcc.8b01118" @default.
• W2789723897 hasPublicationYear "2018" @default.
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