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• W2790070254 abstract "We report the preparation of carbon-based nanomaterials from biopolymer kraft lignin via an iron catalytic thermal treatment process. Both the carbonaceous gases and amorphous carbon (AC) from lignin thermal decomposition were found to have participated in the formation of graphitic-carbon-encapsulated iron nanoparticles (GCEINs). GCEINs originating from carbonaceous gases have thick-walled graphitic-carbon layers (10 to 50) and form at a temperature of 700 °C. By contrast, GCEINs from AC usually have thin-walled graphitic-carbon layers (1 to 3) and form at a temperature of at least 800 °C. Iron catalyst nanoparticles started their phase transition from α-Fe to γ-Fe at 700 °C, and then from γ-Fe to Fe3C at 1000 °C. Furthermore, we derived a formula to calculate the maximum number of graphitic-carbon layers formed on iron nanoparticles via the AC dissolution-precipitation mechanism." @default.
• W2790070254 created "2018-03-29" @default.
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• W2790070254 date "2018-02-13" @default.
• W2790070254 modified "2023-09-28" @default.
• W2790070254 title "Carbon-Based Nanomaterials from Biopolymer Lignin via Catalytic Thermal Treatment at 700 to 1000 °C" @default.
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• W2790070254 doi "https://doi.org/10.3390/polym10020183" @default.
• W2790070254 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6415029" @default.
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