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- W2790102495 abstract "Dotlike, needlelike, and treelike morphologies of N,N′-dicyclohexyl-2,6-naphthalene dicarboxamide (NJS) are induced via self-assembly. Isotactic-polypropylene (iPP)/NJS composite with treelike NJS shows the highest β-iPP relative crystallinity (Kβ). During uniaxial stretching, a higher Kβ could increase the number of voids. However, the size of voids is similar regardless of the NJS morphology. The β-α phase transition takes place after void formation. During intralamellar and interlamellar slip, no obvious polymer chains orientation can be found for α-iPP. In the strain range of 0.1–0.6, the c-axis of the β-iPP crystal tends to orient perpendicular to the stretching direction. This is caused by lamellae twisting, a unique deformation mode of β-iPP lamellae. The lamellae twisting is proposed to be responsible for the intense voids formation of the composite with higher Kβ. At a strain larger than 0.6, the drastic increase of orientation is mainly caused by the rotation of the residual fragmented lamellae and the orientation of the newly formed crystals." @default.
- W2790102495 created "2018-03-29" @default.
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- W2790102495 date "2018-02-01" @default.
- W2790102495 modified "2023-10-07" @default.
- W2790102495 title "Influence of nucleating agent self-assembly on structural evolution of isotactic polypropylene during uniaxial stretching" @default.
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- W2790102495 doi "https://doi.org/10.1016/j.polymer.2018.01.081" @default.
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