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- W279013150 abstract "The influence of 2,2'-bipyridine side-arm of monoazacrown ethers on silver(I) complexation equilibria has been investigated in various non-aqueous solvents. The 2,2'-bipyridyl residue attached to nitrogen atom of the macrocycle significantly controls the formation of 1:1 inclusion-type complexes by stabilizing silver ion inside the cavity. For 1:2 metal-to-ligand complexes, 2,2'-bipyridine unit only slightly increases stability constants of monoaza crown ether complexes. Opposite to the previous report, Ag 2 L 2+ complex has not been observed; instead species of higher complexity, Ag 2 L 3 2 have been found. Their presence has been proved by both spectrophotometry and potentiometry followed by advanced analysis. Studies of monoaza 12-crown ether were performed for comparison with 15- and 18-crown ethers." @default.
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- W279013150 date "2008-01-01" @default.
- W279013150 modified "2023-09-23" @default.
- W279013150 title "An Influence of 2,2'-Bipyridine Side-Arm on Complexation Equilibria of Monoaza Crown Ethers in Various Solvents" @default.
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