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- W2790280462 abstract "[email protected](Fe), with PdAu alloy nanoparticles of ca. 1.7 nm encapsulated inside MIL-100(Fe) cavities, were prepared via a double-solvent impregnation followed by photoreduction. As compared with bare [email protected](Fe), bimetallic [email protected](Fe) showed superior activities for the tandem reactions between amines and alcohols to produce N-alkyl amines under visible-light irradiation, ascribed to the promoting effect of metallic Au in the photocatalytic alcohol-to-aldehyde dehydrogenation. A Pd/Au ratio dependent N-alkylation activity was observed over [email protected](Fe), implying the possibility of synchronizing the reaction rates of two consecutive steps in the N-alkylation reaction, i.e., photocatalytic alcohol-to-aldehyde dehydrogenation and imines hydrogenation, to optimize the whole reaction. This study provides a highly efficient and stable catalytic system for the realization of alkylation of amines via a successful coupling of MOF-based photocatalysis and metal nanoparticle-based hydrogenation. This work also demonstrates that the reaction rates of different catalytic steps in a cascade/tandem reaction can be synchronized for an efficient overall reaction via a rational design of the multifunctional catalysts." @default.
- W2790280462 created "2018-03-29" @default.
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- W2790280462 date "2018-05-01" @default.
- W2790280462 modified "2023-10-18" @default.
- W2790280462 title "PdAu@MIL-100(Fe) cooperatively catalyze tandem reactions between amines and alcohols for efficient N-alkyl amines syntheses under visible light" @default.
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- W2790280462 doi "https://doi.org/10.1016/j.jcat.2018.02.033" @default.
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