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- W2790517241 abstract "Abstract The photophysical properties of lanthanide(III) complexes depend on the magnitude of orbital mixing between the lanthanide(III) and ligands. Herein, an estimation method of orbital mixing in lanthanide(III) complexes is reported using LnCl 3 ⋅ n H 2 O (Ln=Pr, Gd, Tb) and Ln(tfa) 3 (H 2 O) 2 (tfa: trifluoroacetylacetonate, Ln=Pr, Gd, and Tb) for the first time. The electronic state properties were assessed from the electronic absorption and magnetic circular dichroism (MCD) spectra. The MCD spectra revealed the energy levels of the spin‐allowed and spin‐forbidden 4 f–5d transitions of the Tb(III) complex that is hidden by the intense π–π* transition of the ligands. This energy gap corresponds to the exchange splitting energy between the 5d and 4f n−1 electrons, which provides information regarding the orbital mixing between the Tb(III) ion and the ligands." @default.
- W2790517241 created "2018-03-29" @default.
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- W2790517241 date "2018-03-06" @default.
- W2790517241 modified "2023-10-17" @default.
- W2790517241 title "An Estimation Method of Metal-Ligand Orbital Mixing in Lanthanide(III) Complexes Using Magnetic Circular Dichroism" @default.
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- W2790517241 doi "https://doi.org/10.1002/slct.201800050" @default.
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