Matches in SemOpenAlex for { <https://semopenalex.org/work/W2790521019> ?p ?o ?g. }
- W2790521019 abstract "Yields of atomic iodine ${mathrm{I}}^{q+}$ ($qensuremath{ge}2$) fragments resulting from photoexcitation and photoionization of the target ions ${mathrm{IH}}^{+}$ and ${mathrm{I}}^{+}$ have been measured in the photon-energy range 610--680 eV, which comprises the thresholds for iodine $3d$ ionization. The measured ion-yield spectra show two strong and broad resonance features due to the excitation of the $3{d}_{3/2,5/2}$ electrons into $ensuremath{varepsilon}f$ states rather similar for both parent ions. In the $3d$ pre-edge range, excitations into $(npphantom{rule{0.16em}{0ex}}ensuremath{pi})$-like orbitals and into an additional ${ensuremath{sigma}}^{*}$ orbital are found for ${mathrm{IH}}^{+}$, which have been identified by comparison of the atomic ${mathrm{I}}^{+}$ and molecular ${mathrm{IH}}^{+}$ data and with the help of (time-dependent) density functional theory (DFT) and atomic Hartree-Fock calculations. The $(5pphantom{rule{0.16em}{0ex}}ensuremath{pi})$ orbital is almost atomlike, whereas all other resonances of the ${mathrm{IH}}^{+}$ primary ion show a more pronounced molecular character, which is deduced from the chemical shifts of the resonances and the theoretical analysis." @default.
- W2790521019 created "2018-03-29" @default.
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- W2790521019 date "2018-03-01" @default.
- W2790521019 modified "2023-10-17" @default.
- W2790521019 title "Photoabsorption of the molecular IH cation at the iodine<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mn>3</mml:mn><mml:mi>d</mml:mi></mml:mrow></mml:math>absorption edge" @default.
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- W2790521019 doi "https://doi.org/10.1103/physreva.97.033401" @default.
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