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• W2790682790 endingPage "1365" @default.
• W2790682790 startingPage "1357" @default.
• W2790682790 abstract "Abstract Pseudohalogenogermylenes [( i Bu) 2 ATI]GeY (Y=NCO 4 , NCS 5 ) show different coordination behavior towards group 6 metal carbonyls in comparison to the corresponding halogenogermylenes [( i Bu) 2 ATI]GeX (X=F 1 , Cl 2 , Br 3 ) (ATI=aminotroponiminate). The reactions of compounds 4 – 5 and 1 – 3 with cis ‐[M(CO) 4 (COD)] (M=Mo, W, COD=cyclooctadiene) gave trans ‐germylene metal complexes {[( i Bu) 2 ATI]GeY} 2 M(CO) 4 (Y=NCO, M=Mo 6 , W 11 ; Y=NCS, M=Mo 7 ) and cis ‐germylene metal complexes {[( i Bu) 2 ATI]GeX} 2 M(CO) 4 (M=Mo, X=F 8 , Cl 9 , Br 10 ; M=W, X=Cl 12 ), respectively. Theoretical studies on compounds 7 and 9 reveal that donor–acceptor interactions from Mo to Ge atoms are better stabilized in the observed trans and cis geometries than in the hypothetical cis and trans structures, respectively." @default.
• W2790682790 created "2018-03-29" @default.
• W2790682790 creator A5031211319 @default.
• W2790682790 creator A5044336524 @default.
• W2790682790 creator A5052372563 @default.
• W2790682790 creator A5054818199 @default.
• W2790682790 creator A5057439025 @default.
• W2790682790 creator A5073630068 @default.
• W2790682790 date "2018-05-02" @default.
• W2790682790 modified "2023-09-30" @default.
• W2790682790 title "Pseudohalogenogermylenes versus Halogenogermylenes: Difference in their Complexation Behavior towards Group 6 Metal Carbonyls" @default.
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