FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2790732540> ?p ?o ?g. }

• W2790732540 endingPage "430" @default.
• W2790732540 startingPage "419" @default.
• W2790732540 abstract "To expand the use of unsaturated polyester (UP), its flame retardation, thermostability, and glass transition temperature (Tg) must be improved. To achieve this purpose, a novel organophosphorus polymeric flame retardant, poly(hydroxyphenyl imino methyl phenol spirocyclic pentaerythritol diphosphonate) (PPISP), containing both Schiff base and spirocyclic diphosphate structures, has been designed and synthesized. When PPISP is incorporated into the UP matrix, the cured UP thermoset containing 20 wt% PPISP exhibits a much higher initial decomposition temperature (T5%) and Tg than pure UP. Simultaneously, the thermoset composite possesses a limiting oxygen index (LOI) value of 28.2% and achieves a UL-94 V-0 rating as well as sharply decreases the peak heat release rate by 60%. These results demonstrate that PPISP dramatically enhances the flame retardancy of UP. Additionally, the flame-retardant UP (FRUP) exhibits outstanding durable flame-retardance and water resistance. The catalytic charring effect and crosslinking behavior of PPISP are confirmed by thermogravimetric analysis (TGA) and TGA/DSC simultaneous thermal analysis. These analyses reveal that the Schiff base structure and spirocyclic diphosphate groups jointly contribute to the enhancement of the thermal stability of UP. The char layer of UP containing PPISP forms an extraordinary network structure with a stable graphitic microstructure, which acts as a protective barrier during pyrolysis and combustion. The TG-IR and Py-GC/MS results confirm that PPISP mainly takes effect in the condensed phase via catalytic carbonization and aromatization." @default.
• W2790732540 created "2018-03-29" @default.
• W2790732540 creator A5018892762 @default.
• W2790732540 creator A5054795101 @default.
• W2790732540 creator A5062377218 @default.
• W2790732540 creator A5075158998 @default.
• W2790732540 date "2018-07-01" @default.
• W2790732540 modified "2023-10-13" @default.
• W2790732540 title "Highly thermostable and durably flame-retardant unsaturated polyester modified by a novel polymeric flame retardant containing Schiff base and spirocyclic structures" @default.
• W2790732540 cites W1099166916 @default.
• W2790732540 cites W1682928482 @default.
• W2790732540 cites W1882523267 @default.
• W2790732540 cites W1955557829 @default.
• W2790732540 cites W1971308672 @default.
• W2790732540 cites W1979343804 @default.
• W2790732540 cites W1985730713 @default.
• W2790732540 cites W1992469118 @default.
• W2790732540 cites W1993137421 @default.
• W2790732540 cites W2008854263 @default.
• W2790732540 cites W2013790014 @default.
• W2790732540 cites W2028673713 @default.
• W2790732540 cites W2032121930 @default.
• W2790732540 cites W2032349952 @default.
• W2790732540 cites W2034599454 @default.
• W2790732540 cites W2049263671 @default.
• W2790732540 cites W2052125288 @default.
• W2790732540 cites W2058272047 @default.
• W2790732540 cites W2066931959 @default.
• W2790732540 cites W2088073815 @default.
• W2790732540 cites W2095091074 @default.
• W2790732540 cites W2105821930 @default.
• W2790732540 cites W2122129685 @default.
• W2790732540 cites W2137029191 @default.
• W2790732540 cites W2151939010 @default.
• W2790732540 cites W2159697884 @default.
• W2790732540 cites W2168536872 @default.
• W2790732540 cites W2290921748 @default.
• W2790732540 cites W2291864203 @default.
• W2790732540 cites W2313321233 @default.
• W2790732540 cites W2316723908 @default.
• W2790732540 cites W2338114879 @default.
• W2790732540 cites W2364958321 @default.
• W2790732540 cites W2513892464 @default.
• W2790732540 cites W2527984808 @default.
• W2790732540 cites W2565362560 @default.
• W2790732540 cites W2608148753 @default.
• W2790732540 cites W2610399844 @default.
• W2790732540 cites W2625206280 @default.
• W2790732540 cites W268719579 @default.
• W2790732540 cites W4253037819 @default.
• W2790732540 doi "https://doi.org/10.1016/j.cej.2018.03.102" @default.
• W2790732540 hasPublicationYear "2018" @default.
• W2790732540 type Work @default.
• W2790732540 sameAs 2790732540 @default.
• W2790732540 citedByCount "106" @default.
• W2790732540 countsByYear W27907325402019 @default.
• W2790732540 countsByYear W27907325402020 @default.
• W2790732540 countsByYear W27907325402021 @default.
• W2790732540 countsByYear W27907325402022 @default.
• W2790732540 countsByYear W27907325402023 @default.
• W2790732540 crossrefType "journal-article" @default.
• W2790732540 hasAuthorship W2790732540A5018892762 @default.
• W2790732540 hasAuthorship W2790732540A5054795101 @default.
• W2790732540 hasAuthorship W2790732540A5062377218 @default.
• W2790732540 hasAuthorship W2790732540A5075158998 @default.
• W2790732540 hasConcept C119394753 @default.
• W2790732540 hasConcept C122865956 @default.
• W2790732540 hasConcept C127413603 @default.
• W2790732540 hasConcept C159985019 @default.
• W2790732540 hasConcept C160434732 @default.
• W2790732540 hasConcept C171359207 @default.
• W2790732540 hasConcept C178790620 @default.
• W2790732540 hasConcept C185592680 @default.
• W2790732540 hasConcept C188027245 @default.
• W2790732540 hasConcept C192562407 @default.
• W2790732540 hasConcept C205474432 @default.
• W2790732540 hasConcept C2776428424 @default.
• W2790732540 hasConcept C2777325870 @default.
• W2790732540 hasConcept C2778420591 @default.
• W2790732540 hasConcept C2779970684 @default.
• W2790732540 hasConcept C36759035 @default.
• W2790732540 hasConcept C42360764 @default.
• W2790732540 hasConcept C521977710 @default.
• W2790732540 hasConcept C59061564 @default.
• W2790732540 hasConcept C60100273 @default.
• W2790732540 hasConcept C73546260 @default.
• W2790732540 hasConceptScore W2790732540C119394753 @default.
• W2790732540 hasConceptScore W2790732540C122865956 @default.
• W2790732540 hasConceptScore W2790732540C127413603 @default.
• W2790732540 hasConceptScore W2790732540C159985019 @default.
• W2790732540 hasConceptScore W2790732540C160434732 @default.
• W2790732540 hasConceptScore W2790732540C171359207 @default.
• W2790732540 hasConceptScore W2790732540C178790620 @default.
• W2790732540 hasConceptScore W2790732540C185592680 @default.
• W2790732540 hasConceptScore W2790732540C188027245 @default.
• W2790732540 hasConceptScore W2790732540C192562407 @default.
• W2790732540 hasConceptScore W2790732540C205474432 @default.
• W2790732540 hasConceptScore W2790732540C2776428424 @default.

• next