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- W2790752853 abstract "A Pd(II)-catalyzed denitrogenative and desulfinative addition of arylsulfonyl hydrazides with nitriles has been successfully achieved under mild conditions. This transformation is a new method for the addition reaction to nitriles with arylsulfonyl hydrazides as arylating agent, thus providing an alternative synthesis of aryl ketones. The reported addition reaction is tolerant to many common functional groups, and works well in the presence of electron-donating and electron-withdrawing substituents. Notably, the reported denitrogenative and desulfinative addition was also appropriate for alkyl nitriles, making this newly developed transformation attractive." @default.
- W2790752853 created "2018-03-29" @default.
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- W2790752853 date "2018-03-05" @default.
- W2790752853 modified "2023-10-14" @default.
- W2790752853 title "Pd(II)-Catalyzed Denitrogenative and Desulfinative Addition of Arylsulfonyl Hydrazides with Nitriles" @default.
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- W2790752853 doi "https://doi.org/10.1021/acs.joc.8b00211" @default.
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