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- W2791059701 abstract "Five coordination polymers, namely, [Cd(µ3–5-nip)(µ-obix)]n (1), [Co(µ3–5-nip)(µ-obix)]n (2), [Zn(µ−5-nip)(µ-obix)]n (3 and 4) and [Cd(µ−5-nip)(µ-bisobix)]n (5) (5-nip: 5-nitroisophthalate, obix: 1,2-bis(imidazol-1ylmethyl)benzene, bisobix: 1,2-bis(2-isopropylimidazol-1ylmethyl)benzene) were hydrothermally synthesized and characterized by IR spectroscopy, elemental analysis, single crystal and powder X-ray diffraction and thermal analysis (TG/DTA). X-ray results showed that the complexes displayed structural diversity depending on metal ions and conformations of bis(imidazole) linkers. Complexes 1 and 2 were 1D structures and obix ligand displayed cis-conformation. Complexes 3 and 4 exhibited 2D and 3D structures with same components depending on obix conformation. In complex 5, 3D+3D→3D interpenetrated structure was obtained with dia topology when bisobix having sterically hindered groups on imidazole rings was used. Moreover, thermal, photoluminescence and optical properties of the complexes were also investigated." @default.
- W2791059701 created "2018-03-29" @default.
- W2791059701 creator A5020639819 @default.
- W2791059701 date "2018-06-01" @default.
- W2791059701 modified "2023-09-23" @default.
- W2791059701 title "Construction, Structural Diversity and Properties of Five Coordination Polymers Based on 5-Nitroisophthalate and Bis(imidazole) Linkers" @default.
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- W2791059701 doi "https://doi.org/10.1016/j.jssc.2018.03.013" @default.
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