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- W2791221409 endingPage "1159" @default.
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- W2791221409 abstract "Two series of ligand precursors, based on imidazo[1,2-a]pyridine and C2-phenyl substituted imidazole moieties, were developed and synthesized in high yields, featuring an N-CH2(C═O)Ar substituent on the imidazole ring. Upon reacting with palladium acetate, both series of ligands underwent double C–H bond activations at the methylene and o-aryl carbon sites on the N-CH2(C═O)Ar substituent, yielding C,C-type palladacycles bearing five-membered chelate rings. A dimeric palladium complex with bridging bromides was obtained from the ligand precursor with the bromide anion, whereas an ionic palladium complex with two “throw away” pyridine ligands was formed with the precursor of the tetrafluoroborate anion. All complexes are air-stable and were characterized by 1H and 13C NMR spectroscopy and elemental analysis. The structures of three of the new complexes were further established by single-crystal X-ray diffraction studies. These complexes have been screened for catalyzing Mizoroki–Heck coupling reaction using..." @default.
- W2791221409 created "2018-03-29" @default.
- W2791221409 creator A5063904325 @default.
- W2791221409 creator A5076282871 @default.
- W2791221409 date "2018-03-22" @default.
- W2791221409 modified "2023-09-29" @default.
- W2791221409 title "Synthesis and Characterization of <i>C</i>,<i>C</i>-Type Palladacycles and Their Catalytic Application in Mizoroki–Heck Coupling Reaction" @default.
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- W2791221409 doi "https://doi.org/10.1021/acs.organomet.8b00054" @default.
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