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- W2791340201 abstract "Dimethylamine borane (DMAB) has been considered as one of the important hydrogen sources with a simple process by the help of the efficient catalyst. For this purpose, herein, platinum nanoparticles (Pt NPs), placed inside carbon black hybrid (Pt NPs@CBH), activated carbon (Pt NPs@AC) and Vulcan carbon (Pt NPs@VC), have been prepared as highly monodisperse catalysts for dehydrogenation reactions of DMAB at room temperature. The morphological and physical structure of the monodisperse catalysts have been identified by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) etc. The typical face-centered cubic (fcc) structure of the all prepared catalysts was verified from X-ray diffractogram. All prepared catalytic materials were measured as high-performance catalysts for dehyrocoupling of DMAB; but, Pt NPs@CBH catalyst indicated the better catalytic activity compared to the other prepared ones. Easy utilization at very small concentrations and temperature, monodisperse Pt NPs@CBH perform an eye-catching catalytic activity with providing one of the best TOF (70.28 h-1) and Ea (93.56 ± 2 kJ/mol) for dehydrocoupling of DMAB." @default.
- W2791340201 created "2018-03-29" @default.
- W2791340201 creator A5023431656 @default.
- W2791340201 creator A5067601472 @default.
- W2791340201 creator A5071531638 @default.
- W2791340201 date "2018-06-01" @default.
- W2791340201 modified "2023-10-16" @default.
- W2791340201 title "Highly efficient monodisperse Pt nanoparticles confined in the carbon black hybrid material for hydrogen liberation" @default.
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- W2791340201 doi "https://doi.org/10.1016/j.jcis.2018.03.004" @default.
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