Matches in SemOpenAlex for { <https://semopenalex.org/work/W2791465130> ?p ?o ?g. }
- W2791465130 endingPage "39" @default.
- W2791465130 startingPage "27" @default.
- W2791465130 abstract "Abstract Interest in perovskite type oxides is growing due to their versatile catalytic applications. A series of Ruddlesden-Popper (RP) type layered perovskite oxides Srn+1Tin−xNixO3n+1 were prepared and evaluated for their catalytic activity in steam reforming, CO2 reforming and bi-reforming of methane. These materials, prepared through citrate gel method were characterized to understand their structure and Ni reducibility. Substitution of Ni in RP phases was established through refinement of XRD powder pattern. During methane reforming, the catalytic activity increased with the order of RP phase of SrTi1−xNixO3−δ (n = ∞). TPR results show variation in Ni reducibility with the order of RP phase, while TPD-O2 study helped to estimate oxygen vacancies. These vacancies seem to influence catalytic activity during methane reforming. Transient pulse experiments show that CO2 dissociates over oxygen vacancies to give CO and oxygen, with later replenishing lattice oxygen in SrTi0.8Ni0.2O3−δ (n = ∞) phases. Highly labile oxygen vacancies generated in the bulk of SrTi0.8Ni0.2O3−δ must be migrating to the surface, helping in the removal of coke formed. Characterization of catalysts after reaction helped in better understanding of coke precursors." @default.
- W2791465130 created "2018-03-29" @default.
- W2791465130 creator A5016489431 @default.
- W2791465130 creator A5054411627 @default.
- W2791465130 creator A5058245946 @default.
- W2791465130 creator A5060971742 @default.
- W2791465130 creator A5086767857 @default.
- W2791465130 date "2018-04-01" @default.
- W2791465130 modified "2023-10-17" @default.
- W2791465130 title "Tuning the dimensionality of layered Srn+1Tin−xNixO3n+1 perovskite structures for improved activity in syngas generation" @default.
- W2791465130 cites W101015286 @default.
- W2791465130 cites W117995326 @default.
- W2791465130 cites W123004500 @default.
- W2791465130 cites W1496473416 @default.
- W2791465130 cites W1646509462 @default.
- W2791465130 cites W1965647931 @default.
- W2791465130 cites W1967302868 @default.
- W2791465130 cites W1967712606 @default.
- W2791465130 cites W1970065659 @default.
- W2791465130 cites W1981613384 @default.
- W2791465130 cites W1985976126 @default.
- W2791465130 cites W1987761856 @default.
- W2791465130 cites W1993911750 @default.
- W2791465130 cites W1997135622 @default.
- W2791465130 cites W2006690869 @default.
- W2791465130 cites W2006700852 @default.
- W2791465130 cites W2009724999 @default.
- W2791465130 cites W2014769425 @default.
- W2791465130 cites W2015257502 @default.
- W2791465130 cites W2016057821 @default.
- W2791465130 cites W2024684945 @default.
- W2791465130 cites W2027831701 @default.
- W2791465130 cites W2039146215 @default.
- W2791465130 cites W2043794658 @default.
- W2791465130 cites W2049964243 @default.
- W2791465130 cites W2051651562 @default.
- W2791465130 cites W2052130597 @default.
- W2791465130 cites W2053278940 @default.
- W2791465130 cites W2053887277 @default.
- W2791465130 cites W2054750261 @default.
- W2791465130 cites W2058756135 @default.
- W2791465130 cites W2059498129 @default.
- W2791465130 cites W2060876993 @default.
- W2791465130 cites W2070033486 @default.
- W2791465130 cites W2071961131 @default.
- W2791465130 cites W2074046138 @default.
- W2791465130 cites W2082468040 @default.
- W2791465130 cites W2082702621 @default.
- W2791465130 cites W2084378931 @default.
- W2791465130 cites W2084851675 @default.
- W2791465130 cites W2094817259 @default.
- W2791465130 cites W2105634030 @default.
- W2791465130 cites W2106683396 @default.
- W2791465130 cites W2114911094 @default.
- W2791465130 cites W2126230165 @default.
- W2791465130 cites W2143173434 @default.
- W2791465130 cites W2298828976 @default.
- W2791465130 cites W2314311638 @default.
- W2791465130 cites W2318760134 @default.
- W2791465130 cites W2331577482 @default.
- W2791465130 cites W2504229114 @default.
- W2791465130 cites W2556488538 @default.
- W2791465130 cites W2728241391 @default.
- W2791465130 cites W2744721608 @default.
- W2791465130 cites W3106248866 @default.
- W2791465130 cites W76900207 @default.
- W2791465130 cites W841126440 @default.
- W2791465130 doi "https://doi.org/10.1016/j.jcat.2018.01.015" @default.
- W2791465130 hasPublicationYear "2018" @default.
- W2791465130 type Work @default.
- W2791465130 sameAs 2791465130 @default.
- W2791465130 citedByCount "18" @default.
- W2791465130 countsByYear W27914651302019 @default.
- W2791465130 countsByYear W27914651302020 @default.
- W2791465130 countsByYear W27914651302021 @default.
- W2791465130 countsByYear W27914651302022 @default.
- W2791465130 countsByYear W27914651302023 @default.
- W2791465130 crossrefType "journal-article" @default.
- W2791465130 hasAuthorship W2791465130A5016489431 @default.
- W2791465130 hasAuthorship W2791465130A5054411627 @default.
- W2791465130 hasAuthorship W2791465130A5058245946 @default.
- W2791465130 hasAuthorship W2791465130A5060971742 @default.
- W2791465130 hasAuthorship W2791465130A5086767857 @default.
- W2791465130 hasConcept C111030470 @default.
- W2791465130 hasConcept C127413603 @default.
- W2791465130 hasConcept C154945302 @default.
- W2791465130 hasConcept C155011858 @default.
- W2791465130 hasConcept C161790260 @default.
- W2791465130 hasConcept C171250308 @default.
- W2791465130 hasConcept C178790620 @default.
- W2791465130 hasConcept C185592680 @default.
- W2791465130 hasConcept C192562407 @default.
- W2791465130 hasConcept C194439259 @default.
- W2791465130 hasConcept C41008148 @default.
- W2791465130 hasConcept C42360764 @default.
- W2791465130 hasConceptScore W2791465130C111030470 @default.
- W2791465130 hasConceptScore W2791465130C127413603 @default.
- W2791465130 hasConceptScore W2791465130C154945302 @default.