FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2791567101> ?p ?o ?g. }

• W2791567101 endingPage "6457" @default.
• W2791567101 startingPage "6442" @default.
• W2791567101 abstract "Abstract Potentiometric speciation studies, mass spectrometry, and DFT calculations helped to predict the various structural possibilities of the dinuclear trivalent lanthanide ion (Ln III , Ln=La, Eu, Tb, Yb, Y) complexes of a novel macrocyclic ligand, m ‐ODO2A‐dimer (H 4 L), to correlate with their luminescence properties and the promoted BNPP and HPNP phosphodiester bond hydrolysis reaction rates. The stability constants of the dinuclear Ln 2 ( m ‐ODO2A‐dimer) complexes and various hydrolytic species confirmed by mass spectrometry were determined. DFT calculations revealed that the Y 2 LH −1 and the Y 2 LH −2 species tended to form structures with the respective closed‐ and open‐form conformations. Luminescence lifetime data for the heterodimetallic TbEuL system confirmed the fluorescence resonance energy transfer from the Tb III to Eu III ion. The internuclear distance R TbEu values were estimated to be in the range of 9.4–11.3 Å (pH 6.7–10.6), which were comparable to those of the DFT calculated open‐form conformations. Multiple linear regression analysis of the k obs data was performed using the equation: k obs,corr. = k obs − k obs,OH = k [Ln 2 LH −1 ]+ k [Ln 2 LH −2 ] for the observed Ln 2 L‐promoted BNPP/HPNP hydrolysis reactions in solution pH from 7 to 10.5 (Ln=Eu, Yb). The results showed that the second‐order rate constants for the Eu 2 LH −2 and Yb 2 LH −2 species were about 50–400 times more reactive than the structural analogous Zn 2 ( m ‐12 N 3 O‐dimer) system." @default.
• W2791567101 created "2018-03-29" @default.
• W2791567101 creator A5005138809 @default.
• W2791567101 creator A5005505888 @default.
• W2791567101 creator A5006376151 @default.
• W2791567101 creator A5018721926 @default.
• W2791567101 creator A5028947557 @default.
• W2791567101 date "2018-04-14" @default.
• W2791567101 modified "2023-09-27" @default.
• W2791567101 title "Dinuclear Lanthanide(III)-<i>m</i>-ODO2A-dimer Macrocyclic Complexes: Solution Speciation, DFT Calculations, Luminescence Properties, and Promoted Nitrophenyl-Phosphate Hydrolysis Rates" @default.
• W2791567101 cites W1829765835 @default.
• W2791567101 cites W1964641397 @default.
• W2791567101 cites W1965461374 @default.
• W2791567101 cites W1969137131 @default.
• W2791567101 cites W1970756979 @default.
• W2791567101 cites W1971136412 @default.
• W2791567101 cites W1971393793 @default.
• W2791567101 cites W1971425914 @default.
• W2791567101 cites W1972025479 @default.
• W2791567101 cites W1972980120 @default.
• W2791567101 cites W1976936226 @default.
• W2791567101 cites W1980620533 @default.
• W2791567101 cites W1983401029 @default.
• W2791567101 cites W1987715285 @default.
• W2791567101 cites W1989292165 @default.
• W2791567101 cites W1989579457 @default.
• W2791567101 cites W1990870114 @default.
• W2791567101 cites W1990922642 @default.
• W2791567101 cites W1992019209 @default.
• W2791567101 cites W1992833730 @default.
• W2791567101 cites W1993194027 @default.
• W2791567101 cites W1994063901 @default.
• W2791567101 cites W1998602887 @default.
• W2791567101 cites W2000223562 @default.
• W2791567101 cites W2001379423 @default.
• W2791567101 cites W2002131961 @default.
• W2791567101 cites W2005095231 @default.
• W2791567101 cites W2006703886 @default.
• W2791567101 cites W2008509128 @default.
• W2791567101 cites W2011632792 @default.
• W2791567101 cites W2011833200 @default.
• W2791567101 cites W2011873700 @default.
• W2791567101 cites W2013560552 @default.
• W2791567101 cites W2016414535 @default.
• W2791567101 cites W2020074807 @default.
• W2791567101 cites W2026286138 @default.
• W2791567101 cites W2028319001 @default.
• W2791567101 cites W2029844962 @default.
• W2791567101 cites W2030376196 @default.
• W2791567101 cites W2037755225 @default.
• W2791567101 cites W2044096824 @default.
• W2791567101 cites W2045067731 @default.
• W2791567101 cites W2046231571 @default.
• W2791567101 cites W2047694967 @default.
• W2791567101 cites W2048145205 @default.
• W2791567101 cites W2050283912 @default.
• W2791567101 cites W2053185102 @default.
• W2791567101 cites W2056697630 @default.
• W2791567101 cites W2059433503 @default.
• W2791567101 cites W2059702586 @default.
• W2791567101 cites W2060981672 @default.
• W2791567101 cites W2061484747 @default.
• W2791567101 cites W2065363341 @default.
• W2791567101 cites W2070011632 @default.
• W2791567101 cites W2072156178 @default.
• W2791567101 cites W2075154080 @default.
• W2791567101 cites W2075159368 @default.
• W2791567101 cites W2075576177 @default.
• W2791567101 cites W2078555746 @default.
• W2791567101 cites W2080117505 @default.
• W2791567101 cites W2081633916 @default.
• W2791567101 cites W2083073535 @default.
• W2791567101 cites W2083309893 @default.
• W2791567101 cites W2083376879 @default.
• W2791567101 cites W2084363574 @default.
• W2791567101 cites W2085172009 @default.
• W2791567101 cites W2087959853 @default.
• W2791567101 cites W2089042986 @default.
• W2791567101 cites W2090738641 @default.
• W2791567101 cites W2092157292 @default.
• W2791567101 cites W2092333041 @default.
• W2791567101 cites W2094517427 @default.
• W2791567101 cites W2100042879 @default.
• W2791567101 cites W2100334495 @default.
• W2791567101 cites W2106283600 @default.
• W2791567101 cites W2111714153 @default.
• W2791567101 cites W2116067918 @default.
• W2791567101 cites W2117435889 @default.
• W2791567101 cites W2123951007 @default.
• W2791567101 cites W2126436235 @default.
• W2791567101 cites W2131803344 @default.
• W2791567101 cites W2133970683 @default.
• W2791567101 cites W2140801977 @default.
• W2791567101 cites W2147381557 @default.
• W2791567101 cites W2153282431 @default.
• W2791567101 cites W2153985789 @default.
• W2791567101 cites W2154606926 @default.
• W2791567101 cites W2159551780 @default.

• next