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- W2791699650 abstract "The preparation of complex functionalized pillar[ n]arenes (PA[ n]s) is challenging by one-pot cocyclization or selective deprotection method. We developed a step-growth cyclo-oligomerization method to synthesize functionalized PA[5]s. Dimers, trimers, and tetramers were synthesized and characterized. With this new method, we were able to prepare three di- and tetrafunctionalized PA[5]s. By using a multistep synthetic strategy, the chance to form constitutional isomers and other by-products was reduced. Therefore, complex tetrafunctionalized PA[5]s were prepared with improved yield." @default.
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- W2791699650 date "2018-03-14" @default.
- W2791699650 modified "2023-10-10" @default.
- W2791699650 title "Step-Growth Cyclo-Oligomerization for the Preparation of Di- and Tetrafunctionalized Pillar[5]arenes" @default.
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- W2791699650 doi "https://doi.org/10.1021/acs.joc.8b00073" @default.
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