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- W2791802608 abstract "Abstract A new highly selective chemosensor for Cu 2+ and S 2− ions, Ethyl 2‐cyano‐3‐(2‐hydroxy‐5‐methyl‐3‐(p‐tolylimino)methyl)phenyl)acrylate) (HL) based on 2, 6‐diformyl‐4‐methylphenol was designed and synthesized. The ligand exhibited excellent sensitivity towards copper ion by the emission quenching even in the presence of other biologically important metal ions. Once HL combine with Cu 2+ it can display a rapid response and high selectivity toward sulfide anion resulting in off‐on sensing via Cu 2+ displacement assay. The signal transduction happen via reversible formation–separation of complex L–Cu and CuS and the complex L−Cu was synthesized by the reaction of HL and Cu 2+ and characterized by single‐crystal X‐ray diffraction and DFT optimization studies. The catecholase like activity for L−Cu complex have been studied by using 3,5‐di‐tertbutylcatechol (3,5‐DTBC) as the substrate." @default.
- W2791802608 created "2018-03-29" @default.
- W2791802608 creator A5044497796 @default.
- W2791802608 creator A5065469404 @default.
- W2791802608 creator A5083504795 @default.
- W2791802608 date "2018-01-29" @default.
- W2791802608 modified "2023-09-27" @default.
- W2791802608 title "A Highly Selective “On-Off-On” Optical Switch for Sequential Detection of Cu<sup>2+</sup> and S<sup>2−</sup> Ions Based on 2, 6-Diformyl-4-methyl Phenol and Catecholase Activity by Its Copper Complex" @default.
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- W2791802608 doi "https://doi.org/10.1002/slct.201702620" @default.
- W2791802608 hasPublicationYear "2018" @default.
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